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Correlation of the properties of ionic conductivity–structure for the RbGaO2 solid electrolyte

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Abstract

The crystal structure of rubidium gallate RbGaO2 in the temperature range of 300–853 K has been investigated using high-temperature neutron diffraction. The channels available for the motion of rubidium cations in the low-temperature and high-temperature modifications of RbGaO2 have been determined using the computer simulation with the TOPOS program. A correlation between the radius of the migration channel cross section and the rubidium cation conductivity has been established.

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Authors and Affiliations

  1. Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, ul. Sofii Kovalevskoi 18, Yekaterinburg, 620990, Russia

    N. V. Proskurnina & V. I. Voronin

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia

    I. F. Berger

  3. Institute of High Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. Akademicheskaya 20, Yekaterinburg, 620990, Russia

    G. Sh. Shekhtman

Authors
  1. N. V. Proskurnina
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  2. V. I. Voronin
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  3. I. F. Berger
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  4. G. Sh. Shekhtman
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Corresponding author

Correspondence to N. V. Proskurnina.

Additional information

Original Russian Text © N.V. Proskurnina, V.I. Voronin, I.F. Berger, G.Sh. Shekhtman, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 12, pp. 2434–2438.

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Proskurnina, N.V., Voronin, V.I., Berger, I.F. et al. Correlation of the properties of ionic conductivity–structure for the RbGaO2 solid electrolyte. Phys. Solid State 58, 2523–2528 (2016). https://doi.org/10.1134/S1063783416120246

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  • DOI: https://doi.org/10.1134/S1063783416120246

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