Abstract
Monodispersed spherical silica particles, including large mesopores (over 10 nm) and macropores (up to 100 nm) were obtained by chemical etching in an autoclave. A method for introducing globular protein myoglobin molecules into the pores is developed. The method of filling is based on a high adsorption capacity of the developed internal pore structure of the particles. The structure and adsorption properties of the materials are studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Rabe, D. Verdes, and S. Seeger, Adv. Colloid Interface Sci. 162, 87 (2011).
H. H. P. Yiu, C. H. Botting, N. P. Botting, and P. A. Wright, Phys. Chem. Chem. Phys. 3, 2983 (2001).
M. Colilla, M. Manzano, and M. Vallet-Regì, Int. J. Nanomed. 3, 403 (2008).
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, T. W. C. Chu, D. H. Olson, and E. W. Sheppard, J. Am. Chem. Soc. 114, 10834 (1992).
D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrick, B. F. Chmelka, and G. D. Stucky, Science (Washington) 279, 548 (1998).
Y. J. Han, G. D. Stucky, and A. Butler, J. Am. Chem. Soc. 121, 9897 (1999).
E. Yu. Trofimova, D. A. Kurdyukov, Yu. A. Kukushkina, M. A. Yagovkina, and V. G. Golubev, Glass Phys. Chem. 37 (4), 378 (2011).
E. Yu. Trofimova, D. A. Kurdyukov, S. A. Yakovlev, D. A. Kirilenko, Yu. A. Kukushkina, A. V. Nashchekin, A. A. Sitnikova, M. A. Yagovkina, and V. G. Golubev, Nanotechnology 24, 155601 (2013).
E. Yu. Stovpiaga, D. A. Kurdyukov, Yu. A. Kukushkina, V. V. Sokolov, and M. A. Yagovkina, Glass Phys. Chem. 41 (3), 316 (2015).
P. Jiang, J. F. Bertone, K. S. Hwang, and V. L. Colvin, Chem. Mater. 11, 2132 (1999).
E. Yu. Trofimova, A. E. Aleksenskii, S. A. Grudinkin, I. V. Korkin, D. A. Kurdyukov, and V. G. Golubev, Colloid J. 73 (4), 546 (2011).
D. A. Eurov, S. A. Grudinkin, D. A. Kurdyukov, A. V. Medvedev, E. Yu. Stovpiaga, and V. G. Golubev, Tech. Phys. Lett. 41 (10), 919 (2015).
J. Niu, S. Zhang, Y. Niu, R. Song, H. Song, X. Chen, J. Zhou, and S. Hong, RSC Adv. 4, 29435 (2014).
E. Yu. Trofimova, S. A. Grudinkin, Yu. A. Kukushkina, D. A. Kurdyukov, A. V. Medvedev, M. A. Yagovkina, and V. G. Golubev, Phys. Solid State 54 (6), 1298 (2012).
J. D. Andrade, Surface and Interfacial Aspects of Biomedical Polymers, Vol. 2: Protein Adsorption (Plenum, New York, 1985).
B. Stuart, Infrared Spectroscopy: Fundamentals and Applications (Wiley, Chichester, West Sussex, England, 2004).
J. Kong and S. Yu, Acta Biochim. Biophys. Sin. (Shanghai) 39, 549 (2007).
D. A. Eurov, S. A. Grudinkin, D. A. Kurdyukov, and V. G. Golubev, Phys. Solid State 57 (10), 2087 (2015).
P. Innocenzi, J. Non-Cryst. Solids 316, 309 (2003).
M. Dong, Z. Wu, M. Lu, Z. Wang, and Z. Li, Int. J. Mol. Sci. 13, 11443 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.Yu. Stovpiaga, S.A. Grudinkin, D.A. Kurdyukov, Yu.A. Kukushkina, A.V. Nashchekin, V.V. Sokolov, D.R. Yakovlev, V.G. Golubev, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 11, pp. 2256–2261.
Rights and permissions
About this article
Cite this article
Stovpiaga, E.Y., Grudinkin, S.A., Kurdyukov, D.A. et al. Monodisperse spherical meso–macroporous silica particles: Synthesis and adsorption of biological macromolecules. Phys. Solid State 58, 2339–2344 (2016). https://doi.org/10.1134/S1063783416110342
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783416110342