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Dilute ferrimagnetism of ilmenites Mn3FeTiSbO9 and Mn4FeTi2SbO12

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Abstract

Metastable solid solutions (SS) Mn3FeTiSbO9 and Mn4FeTi2SbO12 with the ilmenite structure (space group R \(\bar 3\)) have been prepared by quenching at normal conditions. The compositions of the compounds have been justified using EDX spectroscopy and X-ray diffraction. The magnetic properties of SSs have been analyzed by comparison with ferrimagnetic ilmenite Mn2FeSbO6 (T N = 269 K) as a natural mineral and ceramics obtained at high pressure and high temperature. The solid solutions have been characterized as dilute magnetic systems formed as a result of substitution of nonmagnetic cations Ti4+ for a part of Fe3+ and Sb5+ cations. Mn3FeTiSbO9 is considered as a ferromagnetic with T N = 171 K and Mn4FeTi2SbO12 as a magnetic with the concentration of magnetic clusters below the percolation threshold.

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References

  1. Y. Ishikawa and S. I. Akimoto, J. Phys. Soc. Jpn. 13, 1110 (1958).

    Article  ADS  Google Scholar 

  2. N. Dharmaraj, H. C. Park, C. K. Kim, H. Y. Kim, and D. R. Lee, Mater. Chem. Phys. 87, 5 (2004).

    Article  Google Scholar 

  3. K. P. Surendran, A. Wu, P. M. Vilarinho, and V. M. Ferreira, J. Appl. Phys. 107, 114112 (2010).

    Article  ADS  Google Scholar 

  4. D.-U. Kim and M.-S. Gong, Sens. Actuators, B 110, 321 (2005).

    Article  Google Scholar 

  5. Yu. A. Izyumov and R. P. Ozerov, Magnetic Neutron Diffraction (Nauka, Moscow, 1966; Plenum, New York, 1970).

    Google Scholar 

  6. Yu. N. Benevtsev, S. A. Fedulov, Z. I. Shapiro, and V. P. Klyuev, Barium Titanate (Nauka, Moscow, 1973), p. 118 [in Russian].

    Google Scholar 

  7. J. Ko and C. T. Prewitt, Phys. Chem. Miner. 15, 355 (1988).

    Article  ADS  Google Scholar 

  8. C. J. Fennie, Phys. Rev. Lett. 100, 167203 (2008).

    Article  ADS  Google Scholar 

  9. T. Varga, A. Kumar, and E. Vlahos, Phys. Rev. Lett. 103, 047601 (2009).

    Article  ADS  Google Scholar 

  10. A. Aimi, T. Katsumata, D. Mori, D. Fu, M. Itoh, T. Kyômen, K. Hiraki, T. Takahashi, and Y. Inaguma, Inorg. Chem. 50, 6392 (2011).

    Article  Google Scholar 

  11. R. K. Pandey, H. Stern, and W. J. Geerts, Adv. Sci. Technol. 54, 216 (2008).

    Article  Google Scholar 

  12. P. B. Moore, Ark. Mineral. Geol. 4, 449 (1967).

    Google Scholar 

  13. P. B. Moore, Am. Mineral. 53, 1104 (1968).

    Google Scholar 

  14. G. V. Bazuev, B. G. Golovkin, N. V. Lukin, N. I. Kadyrova, and Yu. G. Zainulin, J. Solid State Chem. 124, 333 (1996).

    Article  ADS  Google Scholar 

  15. G. V. Bazuev, B. G. Golovkin, N. I. Kadyrova, and Yu. G. Zuinulin, Dokl. Chem. 353 (4–6), 58 (1997).

    Google Scholar 

  16. R. Mathieu, S. A. Ivanov, G. V. Bazuev, M. Hudl, P. Lasor, I. V. Solovyev, and P. Nordblad, Appl. Phys. Lett. 98, 202505 (2011).

    Article  ADS  Google Scholar 

  17. M. Hudl, R. Mathieu, P. Nordblad, S. A. Ivanov, G. V. Bazuev, and P. Lazor, J. Magn. Magn. Mater. 331, 19 (2013).

    Article  Google Scholar 

  18. M.-R. Li, D. Walker, M. Retuerto, T. Sarkar, J. Hadermann, P. W. Stephens, M. Croft, A. Ignatov, C. P. Grams, J. Hemberger, I. Nowik, P. S. Halasyamani, T. T. Tran, S. Mukherjee, T. S. Dasgupta, et al., Angew. Chem., Int. Ed. 52, 8406 (2013).

    Article  Google Scholar 

  19. G. V. Bazuev and Yu. G. Zainulin, in Proceedings of the 18th International Interdisciplinary Symposium “Order, Disorder, and Properties of Oxides” (ODPO-18), Science and Education Foundation, Rostov-on-Don, 2015, Vol. 1, p. 20.

    Google Scholar 

  20. M.-R. Li, M. Retuerto, Z. Deng, P. W. Stephens, M. Croft, Q. Huang, H. Wu, X. Deng, G. Kotliar, J. Sanchez-Benitez, J. Hadermann, D. Walker, and M. Greenblatt, Angew. Chem. 127, 12237 (2015).

    Article  Google Scholar 

  21. M.-R. Li, M. Retuerto, D. Walker, T. Sarkar, P. W. Stephens, S. Mukherjee, T. S. Dasgupta, J. P. Hodges, M. Croft, C. P. Grams, J. Hemberger, J. Sánchez-Benítez, A. Huq, F. O. Saouma, J. I. Jang, et al., Angew. Chem., Int. Ed. 53, 10774 (2014).

    Article  Google Scholar 

  22. M.-R. Li, M. Croft, P. W. Stephens, D. Vanderbilt, M. Retuerto, Z. Deng, C. P. Grams, J. Hemberger, J. Hadermann, W.-M. Li, C.-Q. Jin, F. O. Saouma, J. I. Jang, H. Akamatsu, V. Gopalan, et al., Adv. Mater. (Weinheim) 27, 2177 (2015).

    Article  Google Scholar 

  23. G. V. Bazuev, A. V. Korolev, I. V. Nikolaenko, and B. G. Golovkin, Dokl. Chem. 462 (Part 2), 141 (2015).

    Article  Google Scholar 

  24. H. G. Scott, J. Solid State Chem. 66, 171 (1987).

    Article  ADS  Google Scholar 

  25. G. V. Bazuev, A. P. Tyutyunnik, and B. G. Golovkin, Z. Anorg. Allg. Chem. 639, 2657 (2013).

  26. R. D. Shannon, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 32, 751 (1976).

    Article  ADS  Google Scholar 

  27. R. Mathieu, S. A. Ivanov, I. V. Solovyev, G. V. Bazuev, P. Anil Kumar, P. Lazor, and P. Nordblad, Phys. Rev. B: Condens. Matter 87, 014408 (2013).

    Article  ADS  Google Scholar 

  28. J. N. Reimers, J. E. Greedan, C. V. Stager, and M. Bjorgvinnsen, Phys. Rev. B: Condens. Matter 47, 5691 (1991).

    Google Scholar 

  29. A. Murasik and G. Roult, J. Phys. (Paris) 25, 522 (1964).

    Article  Google Scholar 

  30. I. Y. Korenblit, E. F. Shender, and B. I. Shklovskii, Phys. Lett. A 46, 275 (1973).

    Article  ADS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia

    G. V. Bazuev & B. G. Golovkin

  2. Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620219, Russia

    A. V. Korolev

Authors
  1. G. V. Bazuev
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  2. A. V. Korolev
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  3. B. G. Golovkin
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Correspondence to G. V. Bazuev.

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Original Russian Text © G.V. Bazuev, A.V. Korolev, B.G. Golovkin, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 7, pp. 1289–1295.

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Bazuev, G.V., Korolev, A.V. & Golovkin, B.G. Dilute ferrimagnetism of ilmenites Mn3FeTiSbO9 and Mn4FeTi2SbO12 . Phys. Solid State 58, 1332–1338 (2016). https://doi.org/10.1134/S1063783416070064

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  • DOI: https://doi.org/10.1134/S1063783416070064

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