Abstract
Diamond films predominantly consisting of plane micrometer-size crystallites with a thickness of several dozen nanometers have been deposited from a methane–hydrogen gas mixture activated by a dc gas discharge. The crystallite structure has been studied by scanning and transmission electron microscopy and diffraction. A possible mechanism of formation of plane crystallites during deposition of diamond from the gas phase has been discussed. It has been shown that the results agree with the theoretical concepts of formation of crystals with a face-centered cubic lattice.
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References
Y. Gogotsi, MRS Bull. 40, 1110 (2015).
D. Goodwin, J. Butler, M. Prelas, G. Popovici, and L. Bigelow, Handbook of Industrial Diamonds and Diamond Films (Marcel Dekker, New York, 1998).
H. Pierson, Handbook of Carbon, Graphite, Diamond and Fullerenes (Noyes, New York, 1993).
A. Albrecht, G. Koplovitz, A. Retzker, F. Jelezko, S. Yochelis, D. Porath, Y. Nevo, O. Shoseyov, Y. Paltiel, and M. B. Plenio, New J. Phys. 16, 093002 (2014).
T. M. Babinec, B. J. Hausmann, M. Khan, Y. Zhang, J. R. Maze, P. R. Hemmer, and M. Loncar, Nat. Nanotechnol. 5, 195 (2010).
M. J. Burek, B. J. Shields, N. P. de Leon, B. Hausmann, Y. Chu, Q. Quan, M. D. Lukin, and M. Loncar, CLEO: Sci. Innovations 1, CM1M. 2 (2012).
J. Gracio, Q. Fan, and J. Madaleno, J. Phys. D: Appl. Phys. 43, 374017 (2010).
F. T. Tuyakova, E. A. Obraztsova, and R. R. Ismagilov, J. Nanophotonics 10, 12517 (2016).
C. Wild, R. Kohl, N. Herres, W. Müller-Sebert, and P. Koidl, Diamond Relat. Mater. 3, 373 (1994).
A. A. Zolotukhin, M. A. Dolganov, A. M. Alekseev, and A. N. Obraztsov, Diamond Relat. Mater. 42, 15 (2014).
A. Zolotukhin, P. G. Kopylov, R. R. Ismagilov, and A. N. Obraztsov, Diamond Relat. Mater. 19, 1007 (2010).
R. R. Ismagilov, I. R. Khamidullin, V. I. Kleshch, S. A. Malykhin, A. M. Alexeev, and A. N. Obraztsov, J. Nanophotonics 10, 12503 (2016).
R. R. Ismagilov, A. A. Zolotukhin, P. V. Shvets, and A. N. Obraztsov, J. Nanoelectron. Optoelectron. 7, 90 (2012).
I. Aharonovich, J. C. Lee, A. P. Magyar, D. O. Bracher, and E. L. Hu, Laser Photonics Rev. 7, L61 (2013).
I. Aharonovich and E. Neu, Adv. Opt. Mater. 2, 911 (2014).
B. Hausmann, B. Shields, Q. Quan, Y. Chu, N. de Leon, R. Evans, M. Burek, A. Zibrov, M. Markham, and D. Twitchen, Nano Lett. 13, 5791 (2013).
M. Kasperczyk, A. Jorio, E. Neu, P. Maletinsky, and L. Novotny, Opt. Lett. 40, 2393 (2015).
J. O. Sofo, A. S. Chaudhari, and G. D. Barber, Phys. Rev. B: Condens. Matter 75, 153401 (2007).
L. A. Chernozatonskii, P. B. Sorokin, A. G. Kvashnin, and D. G. Kvashnin, JETP Lett. 90 (2), 134 (2009).
J. C. Angus, M. Sunkara, S. R. Sahaida, and J. T. Glass, J. Mater. Res. 7, 3001 (1992).
C.-A. Lu and L. Chang, Mater. Chem. Phys. 92, 48 (2005).
C.-A. Lu and L. Chang, Diamond Relat. Mater. 13, 2056 (2004).
B. Spitsyn, L. Bouilov, and B. Derjaguin, J. Cryst. Growth 52, 219 (1981).
D. M. Gruen, Annu. Rev. Mater. Sci. 29, 211 (1999).
R. R. Ismagilov, P. V. Shvets, A. Yu. Kharin, and A. N. Obraztsov, Crystallogr. Rep. 56 (2), 310 (2011).
R. I. Ismagilov, P. V. Shvets, A. A. Zolotukhin, and A. N. Obraztsov, J. Nanoelectron. Optoelectron. 4, 243 (2009).
R. R. Ismagilov, P. V. Shvets, A. A. Zolotukhin, and A. N. Obraztsov, Chem. Vap. Deposition 19, 332 (2013).
B. V. Spitsyn, L. L. Bouilov, and B. V. Derjaguin, Prog. Cryst. Growth Charact. 17, 79 (1988).
D. Seo, C. I. Yoo, I. S. Chung, S. M. Park, S. Ryu, and H. Song, J. Phys. Chem. C 112, 2469 (2008).
L. Marks, J. Cryst. Growth 61, 556 (1983).
G. Wulff, Z. Kristallogr. 34, 449 (1901).
E. Ringe, IUCrJ 1, 530 (2014).
E. Ringe, R. P. Van Duyne, and L. D. Marks, J. Phys. Chem. C 117, 15859 (2013).
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Original Russian Text © A.M. Alexeev, R.R. Ismagilov, E.E. Ashkinazi, A.S. Orekhov, S.A. Malykhin, A.N. Obraztsov, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 7, pp. 1408–1412.
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Alexeev, A.M., Ismagilov, R.R., Ashkinazi, E.E. et al. Quasi-two-dimensional diamond crystals: Deposition from a gaseous phase and structural–morphological properties. Phys. Solid State 58, 1458–1462 (2016). https://doi.org/10.1134/S1063783416070039
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DOI: https://doi.org/10.1134/S1063783416070039