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Determination of the melting temperature of palladium nanoparticles by X-ray absorption spectroscopy

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Abstract

The anharmonicity parameters of the interatomic potential in ~4-nm palladium nanoparticles deposited on poly(tetra)fluoroethylene microgranules 0.2–0.5 μm in average size were studied by X-ray absorption spectroscopy from an analysis of temperature-dependent EXAFS Pd K edges. The parameters of the interatomic potential obtained were used to calculate melting temperature T melt = 1591 K and Debye temperature ΘD = 257 K of palladium nanoparticles; these temperatures are significantly lower than those in metallic palladium: 277 K and 1825 K, respectively.

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, pr. Stachki 194, Rostov-on-Don, 344090, Russia

    V. G. Vlasenko, S. S. Podsukhina & A. V. Kozinkin

  2. National Scientific Center “Kurchatov Institute,”, pl. Kurchatova 1, Moscow, 123098, Russia

    Ya. V. Zubavichus

Authors
  1. V. G. Vlasenko
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  2. S. S. Podsukhina
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  3. A. V. Kozinkin
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  4. Ya. V. Zubavichus
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Correspondence to V. G. Vlasenko.

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Original Russian Text © V.G. Vlasenko, S.S. Podsukhina, A.V. Kozinkin, Ya.V. Zubavichus, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 2, pp. 409–414.

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Vlasenko, V.G., Podsukhina, S.S., Kozinkin, A.V. et al. Determination of the melting temperature of palladium nanoparticles by X-ray absorption spectroscopy. Phys. Solid State 58, 421–426 (2016). https://doi.org/10.1134/S1063783416020335

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  • DOI: https://doi.org/10.1134/S1063783416020335

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