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Partial conductivities in perovskites CaZr1–x Sc x O3–α (x = 0.03–0.20) in an oxidation atmosphere

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Abstract

Partial (ionic, proton, and hole) conductivities of oxides CaZr1–x Sc x O3–α(x = 0.03–0.20) with the perovskite structure in air atmosphere have been studied as functions of temperature in the range of 600–900°C and partial water-vapor pressure in the range of \({P_{{H_2}O}}\)= 40–2500 Pa. The influence of the humidity of the atmosphere on the relative change in the concentration of oxygen vacancies as a function of temperature has been estimated.

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References

  1. S. Stotz and C. Wagner, Ber. Bunsen-Ges. 70 (8), 781 (1966).

    Google Scholar 

  2. N. Fukatsu, N. Kuruta, T. Yajima, K. Koide, and T. Ohashi, J. Alloys Compd. 231, 706 (1995).

    Article  Google Scholar 

  3. K. D. Kreuer, Annu. Rev. Mater. Res. 33, 333 (2003).

    Article  ADS  Google Scholar 

  4. M. Dudek, Adv. Mater. Sci. 8, 15 (2008).

    MathSciNet  Google Scholar 

  5. H. Iwahara, T. Yajima, T. Hibino, and H. Suzuki, Solid State Ionics 61, 65 (1993).

    Article  Google Scholar 

  6. M. Tanaka, K. Katahira, Y. Asakura, T. Uda, H. Iwahara, and I. Yamamoto, J. Nucl. Sci. Technol. 41, 61 (2004).

    Article  Google Scholar 

  7. Ch. Shi, M. Yoshino, and M. Morinaga, Solid State Ionics 176, 1091 (2005).

    Article  Google Scholar 

  8. N. Kurita, Yue-P. Xiong, Y. Imai, and N. Fukatsu, Ionics 16, 787 (2010).

    Article  Google Scholar 

  9. V. P. Gorelov, V. B. Balakireva, A. V. Kuz’min, and S. V. Plaksin, Inorg. Mater. 50 (5), 495 (2014).

    Article  Google Scholar 

  10. V. P. Gorelov, V. B. Vykhodets, T. E. Kurennykh, V. B. Balakireva, A. V. Kuz’min, and M. V. Ananiev, Russ. J. Electrochem. 49 (9), 915 (2013).

    Article  Google Scholar 

  11. V. P. Gorelov and V. B. Balakireva, Neorg. Mater. 26, 102 (1990).

    Google Scholar 

  12. M.V. Anan’ev, N. M. Bershitskaya, S. V. Plaksin, I. V. Korzun, and E. Kh. Kurumchin, Russ. J. Electrochem. 48 (9), 879 (2012).

    Article  Google Scholar 

  13. A. Løken, Ch. Kjølseth, and R. Haugsrud, Solid State Ionics 267, 61 (2014).

    Article  Google Scholar 

  14. E. Vøllestad, H. Zhu, and R. J. Keeb, J. Electrochem. Soc. 161 (1), F114 (2014).

    Article  Google Scholar 

  15. G. I. Fadeev, A. N. Volkov, A. S. Kalyakin, A. K. Demin, V. P. Gorelov, A. D. Neuimin, and V. B. Balakireva, RF Patent No. 2483298, Byull. Izobret., No. 15, 96 (2013).

    Google Scholar 

  16. A. K. Demin, A. N. Volkov, A. S. Kalyakin, G. I. Fadeev, V. P. Gorelov, and A. V. Kuz’min, RF Patent No. 2483300, Byull. Izobret., No 15, 96 (2013).

    Google Scholar 

  17. A. N. Volkov, A. S. Kalyakin, G. I. Fadeev, A. K. Demin, and V. P. Gorelov, RF Patent No. 2490623, Byull. Izobret., No. 23, 96 (2013).

    Google Scholar 

  18. E. C. C. de Souza and R. Muccillo, Mater. Res. 13, 385 (2010).

    Article  Google Scholar 

  19. V. P. Gorelov and V. B. Balakireva, Russ. J. Electrochem. 45 (4), 476 (2009).

    Article  Google Scholar 

  20. A. V. Kuz’min, V. B. Balakireva, S. V. Plaksin, and V. P. Gorelov, Russ. J. Electrochem. 45 (12), 1351 (2009).

    Article  Google Scholar 

  21. V. P. Gorelov, V. B. Balakireva, and A. V. Kuz’min, Russ. J. Electrochem. 46 (8), 890 (2010).

    Article  Google Scholar 

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Correspondence to V. P. Gorelov.

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Original Russian Text © V.P. Gorelov, V.B. Balakireva, A.V. Kuz’min, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 1, pp. 14–20.

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Gorelov, V.P., Balakireva, V.B. & Kuz’min, A.V. Partial conductivities in perovskites CaZr1–x Sc x O3–α (x = 0.03–0.20) in an oxidation atmosphere. Phys. Solid State 58, 12–18 (2016). https://doi.org/10.1134/S1063783416010145

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  • DOI: https://doi.org/10.1134/S1063783416010145

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