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NMR spectra and translational diffusion of protons in crystals with hydrogen bonds

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Abstract

Investigation of proton transport in hydrogen-bond crystals at low temperatures is currently one of important problems in the semiconductor physics. With the use of the NMR spectra of wide-band-gap hydrogen-bond crystals grown in H2O and D2O solutions, we have succeeded in finding a direct proof of the presence of protons in the mobile phase, determined their activation energy in good agreement with the spectra of thermally stimulated depolarization currents and with the infrared spectra, and, as a result, clarified the mechanism of proton transport and tunneling.

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Authors and Affiliations

  1. Admiral Ushakov State Maritime University, pr. Lenina 93, Novorossisk, 353918, Russia

    V. M. Timokhin

  2. National University of Science and Technology “MISiS”, Leninskii pr. 4, Moscow, 119049, Russia

    V. M. Timokhin & V. M. Garmash

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. P. Tarasov

Authors
  1. V. M. Timokhin
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  2. V. M. Garmash
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  3. V. P. Tarasov
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Correspondence to V. M. Timokhin.

Additional information

Original Russian Text © V.M. Timokhin, V.M. Garmash, V.P. Tarasov, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 7, pp. 1290–1293.

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Timokhin, V.M., Garmash, V.M. & Tarasov, V.P. NMR spectra and translational diffusion of protons in crystals with hydrogen bonds. Phys. Solid State 57, 1314–1317 (2015). https://doi.org/10.1134/S1063783415070331

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  • DOI: https://doi.org/10.1134/S1063783415070331

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