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X-ray photoelectron spectroscopy investigation of the mechanism of formation of carbine in nanomodified polyvinyl alcohol

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Abstract

The modification of polyvinyl alcohol by nickel/carbon nanostructures and the effect of their composition on the change in the polymer structure have been investigated using X-ray photoelectron spectroscopy. It has been shown that, at concentrations of the nanostructures from 1 to 90%, the structure of the first energy level of the carbon atom (C 1s) of the polymer spectrum changes: carbon-carbon bonds with sp-, sp 2-, and sp 3-hybridizations of valence electrons are formed, whereas bonds of the carbon atoms with oxygen or hydrogen are absent. The formation of carbon bonds with sp-hybridization of valence electrons (carbine) leads to an increase in the current-conducting characteristics of the polymer.

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Authors and Affiliations

  1. Physical-Technical Institute, Ural Branch of the Russian Academy of Sciences, ul. Kirova 132, Izhevsk, Republic of Udmurtia, 426000, Russia

    I. N. Shabanova, V. A. Trapeznikov, N. S. Terebova & G. V. Sapozhnikov

  2. Udmurt State University, ul. Universitetskaya 1, Izhevsk, Republic of Udmurtia, 426034, Russia

    I. N. Shabanova, V. A. Trapeznikov, N. S. Terebova & G. V. Sapozhnikov

Authors
  1. I. N. Shabanova
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  2. V. A. Trapeznikov
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  3. N. S. Terebova
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  4. G. V. Sapozhnikov
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Correspondence to I. N. Shabanova.

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Original Russian Text © I.N. Shabanova, V.A. Trapeznikov, N.S. Terebova, G.V. Sapozhnikov, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 7, pp. 1442–1444.

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Shabanova, I.N., Trapeznikov, V.A., Terebova, N.S. et al. X-ray photoelectron spectroscopy investigation of the mechanism of formation of carbine in nanomodified polyvinyl alcohol. Phys. Solid State 57, 1469–1471 (2015). https://doi.org/10.1134/S1063783415070264

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  • DOI: https://doi.org/10.1134/S1063783415070264

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