Abstract
A technique for determining parameters of the local atomic structure of a manganese-oxygen system by the extended energy loss fine structure method has been proposed. Experimental extended energy loss fine structure spectra of the clean surface of metallic manganese and its stoichiometric oxides have been measured. Normalized oscillating portions have been separated from the experimental spectra and analyzed by solving the inverse problem using the Tikhonov regularization. The parameters of the local atomic structure of the objects under study, i.e., coordination numbers, bond lengths, and their variance parameters, have been determined.
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References
B. M. Kincaid, A. E. Meixner, and P. M. Platzman, Phys. Rev. Lett. 40, 1296 (1978).
J. J. Ritsko, P. C. Gibbons, and S. E. Schnattery, Phis. Rev. Lett. 32, 671 (1974).
R. D. Leapman, I. A. Grunes, and P. L. Fejes, Phys. Rev. B: Condens. Matter 26, 541 (1982).
M. DeCrescenzi, L. Papagno, and G. Chiarello, Solid State Commun. 40, 613 (1987).
M. De Crescenzi, Crit. Rev. Solid State Mater. Sci. 15(3), 279 (1989).
M. De Crescenzi, Surf. Sci. Rep. 21, 89 (1995).
T. Fujikawa, Electron Energy Loss Spectroscopy for Surface Study: Handbook of Thin Film Materials (Elsevier, Amsterdam, 2000), Vol. 2, p. 415.
D. I. Kochubei, Yu. A. Babanov, K. I. Zamaraev, and R. V. Vedrinskii, X-Ray Diffraction Method of Investigation of the Structure of Amorphous Solids (Nauka, Novosibirsk, 1988) [in Russian].
B. V. Andryushechkin, K. N. El’tsov, and A. N. Klimov, Tr. Inst. Obshch. Fiz. im. A. M. Prokhorova, Russ. Akad. Nauk 59, 23 (2003).
D. E. Guy, D. V. Surnin, A. N. Deev, and Yu. V. Ruts, J. Electron Spectrosc. Relat. Phenom. 95, 193 (1998).
Yu. V. Ruts, D. E. Guy, D. V. Surnin, and V. I. Grebennikov, in Handbook of Surfaces and Interfaces of Materials, Ed. by H. S. Nalwa, Vol. 2: Surface and Interface Analysis and Properties (Elsevier, Amsterdam, 2001), Chap. 14, p. 1.
D. E. Gai, V. I. Grebennikov, D. V. Surnin, and O. R. Zheltysheva, Poverkhnost, No. 11, 81 (2003).
O. R. Zheltysheva, D. E. Guy, D. V. Surnin, Y. V. Ruts, and V. I. Grebennikov, Nucl. Instrum. Methods Phys. Res., Sect. A 543, 244 (2005).
E. Clementi, C. C. J. Roothaan, and M. Yoshimine, Phys. Rev. 127(5), 1618 (1962).
E. Clementi and C. Roetti, At. Data Nucl. Data Tables 14, 11760 (1974).
J. J. Rehr and R. C. Albers, Rev. Mod. Phys. 72(3), 621 (2000).
A. L. Ageev, N. V. Ershov, V. R. Shvetsov, Yu. A. Babanov, and V. V. Vasin, Length of Chemical Bond: A Complex of X-Ray Diffraction Data Processing Programs (Institute of Mathematics and Mechanics, Ural Scientific Center of the Academy of Sciences of the USSR, Sverdlovsk, 1987) [in Russian].
A. P. Babichev, N. A. Babushkina, A. M. Bratkovskii, et al., in Handbook of Physical Quantities, Ed. by I. S. Grigoriev and E. Z. Melikhov (Energoatomizdat, Moscow, 1991; CRC Press, Boca Raton, Florida, United States, 1997).
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Original Russian Text © O.R. Bakieva, O.M. Nemtsova, D.V. Surnin, D.E. Gai, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 7, pp. 1420–1429.
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Bakieva, O.R., Nemtsova, O.M., Surnin, D.V. et al. Analysis of the local atomic structure of manganese and its oxides by extended energy loss fine structure spectroscopy. Phys. Solid State 57, 1446–1455 (2015). https://doi.org/10.1134/S1063783415070057
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DOI: https://doi.org/10.1134/S1063783415070057