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Influence of copper impurities on the evolution of the electronic structure and optical spectra of the LuNi5 compound

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Abstract

The optical properties of LuNi5 − x Cu x intermetallic compounds (x = 0, 1, 2) have been investigated using ellipsometry in the wavelength range of 0.22–15 μm. It has been established that the partial substitution of nickel by copper leads to substantial variations in the spectral characteristics, as well as in the plasma and relaxation frequencies of conduction electrons. Self-consistent calculations of the electronic structure of these compounds have been performed in the approximation of the local electron spin density. The experimental frequency dependences of the optical conductivity in the interband optical absorption region have been interpreted based on the calculated densities of electron states.

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References

  1. K. A. Gschneidner, Jr, V. K. Pecharsky, and A. O. Tsokol, Rep. Prog. Phys. 68, 1479 (2005).

    Article  ADS  Google Scholar 

  2. Concise Encyclopedia of Magnetic and Superconducting Materials, Ed. by K. H. J. Buschow (Elsevier, Amsterdam, 2005).

  3. P. J. von Ranke, M. A. Mota, D. F. Grangeia, A. Magnus, G. Carvalho, F. C. G. Gandra, A. A. Coelho, A. Caldas, N. A. de Oliveira, and S. Gama, Phys. Rev. B: Condens. Matter 70, 134428 (2004).

    Article  ADS  Google Scholar 

  4. D. L. Rocco, J. S. Amaral, J. V. Leitão, V. S. Amaral, M. S. Reis, S. Das, R. P. Fernandes, J. P. Arau’jo, A. M. Pereira, P. B. Tavares, N. V. Martins, and A. A. Coelho, J. Phys. D: Appl. Phys. 42, 055002 (2009).

    Article  ADS  Google Scholar 

  5. H. Senoh, N. Takeichi, H. T. Takeshita, H. Tanaka, T. Kiyobayashi, and N. Kuriyama, Mater. Sci. Eng., B 108, 96 (2004).

    Article  Google Scholar 

  6. X. Zhao and L. Ma, Int. J. Hydrogen Energy 34, 4788 (2009).

    Article  Google Scholar 

  7. A. G. Kuchin, A. S. Ermolenko, Yu. A. Kulikov, V. I. Khrabrov, E. V. Rosenfeld, G. M. Makarova, T. P. Lapina, and Ye. V. Belozerov, J. Magn. Magn. Mater. 303, 119 (2006).

    Article  ADS  Google Scholar 

  8. L. Romaka, V. Romaka, and Yu. Stadnyk, Chem. Met. Alloys 4, 89 (2011).

    Google Scholar 

  9. L. Guénée, and K. Yvon, J. Alloys Compd. 356–357, 114 (2003).

    Article  Google Scholar 

  10. K. H. J. Buschow, Rep. Prog. Phys. 40, 1179 (1977).

    Article  ADS  Google Scholar 

  11. O. K. Andersen and O. Jepsen, Phys. Rev. Lett. 53, 2571 (1984).

    Article  ADS  Google Scholar 

  12. A. Bajorek, G. Chełkowska, and B. Andrzejewski, J. Alloys Compd. 509, 578 (2011).

    Article  Google Scholar 

  13. Yu. V. Knyazev, A. V. Lukoyanov, Yu. I. Kuz’min, and A. G. Kuchin, J. Alloys Compd. 509, 5238 (2011).

    Article  Google Scholar 

  14. Yu. V. Knyazev, A. V. Lukoyanov, Yu. I. Kuz’min, and A. G. Kuchin, Phys. Status Solidi B 249, 824 (2012).

    Article  ADS  Google Scholar 

  15. C. N. Berglund and W. E. Spicer, Phys. Rev. 136, A1044 (1964).

    Article  ADS  Google Scholar 

  16. M. I. Kaganov and V. V. Slezov, Sov. Phys. JETP 5, 1216 (1957).

    MATH  Google Scholar 

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Correspondence to Yu. V. Knyazev.

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Original Russian Text © Yu.V. Knyazev, A.V. Lukoyanov, Yu.I. Kuz’min, A.G. Kuchin, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 5, pp. 853–856.

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Knyazev, Y.V., Lukoyanov, A.V., Kuz’min, Y.I. et al. Influence of copper impurities on the evolution of the electronic structure and optical spectra of the LuNi5 compound. Phys. Solid State 57, 866–870 (2015). https://doi.org/10.1134/S1063783415050145

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