Abstract
This paper presents the results of a complex investigation of heterogeneous systems based on multiwalled carbon nanotubes with the outer surfaces covered by iron oxide (Fe3O4) nanocoatings deposited using iron pentacarbonyl as a precursor. Investigations were performed by the methods of electron microscopy, X-ray diffractometry, and ultrasoft X-ray spectroscopy with synchrotron radiation. It was established that the formed thin coatings are continuous and nonuniform in thickness. It was shown that good adhesion of iron oxide on the multiwalled carbon nanotube surface is provided by the formation of epoxy and double carbon-oxygen bonds; in this case, the outer graphene layer of nanotubes is not destroyed and retains the hexagonal structure.
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W. M. Daoush, B. K. Lim, C. B. Mo, D. H. Nam, and S. H. Hong, Mater. Sci. Eng., A 513–514, 247 (2009).
C. N. R. Rao and A. K. Cheetham, J. Mater. Chem. 11,2887 (2001).
D. Eder, Chem. Rev. 110, 1348 (2010).
Q. Liu, W. Ren, Z.-G. Chen, B. Liu, B. Yu, F. Li, H. Cong, and H.-M. Cheng, Carbon 46, 1417 (2008).
A. I. Kirillov, A. M. Ob”edkov, V. A. Egorov, G. A. Domrachev, B. S. Kaverin, N. M. Semenov, T. I. Lopatina, S. A. Gusev, and A. D. Mansfel’d, Nanotekhnika, No. 1, 72 (2011).
V. N. Sivkov, O. V. Petrova, S. V. Nekipelov, A. M. Obiedkov, B. S. Kaverin, A. I. Kirillov, N. M. Semenov, G. A. Domrachev, V. A. Egorov, S. A. Gusev, D. V. Vyalikh, and S. L. Molodtsov, in Proceedings of the Eleventh Biennial Conference on High-Resolution X-Ray Diffraction and Imaging (XTOP-2012), St. Petersburg, Russia, September 15–20, 2012 (St. Petersburg, 2012), Vol. 1, p. 411.
V. N. Sivkov, A. A. Lomov, A. L. Vasil’ev, S. V. Nekipelov, and O. V. Petrova, Semiconductors 47(8), 1051 (2013).
S. I. Fedoseenko, D. V. Vyalikh, I. E. Iossifov, R. Follath, S. A. Gorovikov, R. Puttner, J.-S. Schmidt, S. L. Molodtsov, V. K. Adamchuk, W. Gudat, and G. Kaindl, Nucl. Instrum. Methods Phys. Res., Sect. A 505, 718 (2003).
K. Kummer, V. N. Sivkov, D. V. Vyalikh, V.V. Maslyuk, A. Bluher, S.V. Nekipelov, T. Bredow, I. Mertig, M. Mertig, and S. L. Molodtsov, Phys. Rev. B: Condens. Matter 80, 155433–11 (2009).
A. M. Ob”edkov, B. S. Kaverin, V. A. Egorov, N. M. Semenov, S. Yu. Ketkov, G. A. Domrachev, K. V. Kremlev, S. A. Gusev, V. N. Perevezentsev, A. N. Moskvichev, A. A. Moskvichev, and A. S. Rodionov, Pis’ma Mater. 2, 152 (2012).
J. Stohr, NEXAFS-Spectroscopy (Springer-Verlag, Berlin, 1992), Chap. 5, p. 122.
S. A. Gorovikov, S. L. Molodtsov, and R. Follath, Nucl. Instrum. Methods Phys. Res., Sect. A 441, 506 (1998).
B. L. Henke, E. M. Gullikson, and J. L. Devis, At. Data Nucl. Data Tables 54, 181 (1993).
K. Kuepper, I. Balasz, H. Hesse, A. Winiarski, K. C. Prince, M. Matteucci, D. Wett, R. Szargan, E. Burzo, and M. Neumann, Phys. Status Solidi A 201(15), 3252 (2004).
S. A. Krasnikov, A. S. Vinogradov, K.-H. Hallmeier, Ziese R. Höhn, P. Esquinazi, T. Chassé, and R. Szargan, Mater. Sci. Eng., B 109, 207 (2004).
H.-K. Jeong, H.-J. Noh, J.-Y. Kim, M. H. Jin, C. Y. Park, and Y. H. Lee, Eur. Lett. 82, 67004 (2008).
S. Gota, M. Gautier-Soyer, and M. O. Sacchi, Phys. Rev. B: Condens. Matter 62(7), 4187 (2000).
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Original Russian Text © V.N. Sivkov, A.M. Ob”edkov, O.V. Petrova, S.V. Nekipelov, K.V. Kremlev, B.S. Kaverin, N.M. Semenov, S.A. Gusev, 2015, published in Fizika Tverdogo Tela, 2015, Vol. 57, No. 1, pp. 185–191.
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Sivkov, V.N., Ob”edkov, A.M., Petrova, O.V. et al. X-ray and synchrotron investigations of heterogeneous systems based on multiwalled carbon nanotubes. Phys. Solid State 57, 197–204 (2015). https://doi.org/10.1134/S1063783415010291
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DOI: https://doi.org/10.1134/S1063783415010291