Skip to main content
SpringerLink
Log in

Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal

  • Lattice Dynamics
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The infrared absorption spectra of the oxyfluoride Rb2KMoO3F3 have been measured in the frequency range corresponding to stretching vibrations of the Mo-O anion octahedron with the purpose of clarifying their role in the phase transition. A semi-empirical calculation of two possible configurations of quasioctahedral MoO3F3 groups has been performed. The results of the investigations have demonstrated that some octahedra in the crystal structure change the local symmetry from C 3v to C 2v due to the phase transition (T = 197 K).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. I. Pogorel’tsev, E. V. Bogdanov, M. S. Molokeev, V. N. Voronov, L. I. Isaenko, S. A. Zhurkov, N. M. Laptash, M. V. Gorev, and I. N. Flerov, Phys. Solid State 53(6), 1202 (2011).

    Article  ADS  Google Scholar 

  2. K. Von Dehnicke, G. Pausewang, and W. Rudoeff, Z. Anorg. Allg. Chem. 366, 64 (1969).

    Article  Google Scholar 

  3. G. Peraudeau, J. Ravez, and P. Haggenmuller, Solid State Commun. 27, 591 (1978).

    Article  ADS  Google Scholar 

  4. S. C. Abrahams, J. L. Bernstein, and J. Ravez, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 37, 1332 (1981).

    Article  Google Scholar 

  5. J. Ravez, G. Peraudeau, H. Arend, S. C. Abrahams, and P. Haggenmuller, Ferroelectrics 26, 767 (1980).

    Article  Google Scholar 

  6. G. Peraudeau, J. Ravez, and H. Arend, Solid State Commun. 27, 515 (1978).

    Article  ADS  Google Scholar 

  7. M. Couzi, V. Rodriguez, J. P. Chaminade, M. Fouad, and J. Ravez, Ferroelectric 80, 109 (1988).

    Article  Google Scholar 

  8. A. S. Krylov, E. M. Merkusheva, A. N. Vtyurin, and L. I. Isaenko, Phys. Solid State 54(6), 1275 (2012).

    Article  ADS  Google Scholar 

  9. M. B. Smirnov and V. Yu. Kazimirov, LADY: Software for Lattice Dynamics Simulations (JINR Communications, Dubna, 2001), E14-2001-159.

    Google Scholar 

  10. M. Smirnov and R. Baddour-Hadjean, J. Chem. Phys. 121, 2348 (2004).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50-38, Krasnoyarsk, 660036, Russia

    Yu. V. Gerasimova, A. S. Oreshonkov, A. N. Vtyurin, A. A. Ivanenko, A. A. Ershov & E. I. Pogoreltsev

  2. Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia

    L. I. Isaenko

Authors
  1. Yu. V. Gerasimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Oreshonkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Vtyurin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Ivanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. I. Isaenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. A. Ershov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. E. I. Pogoreltsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. V. Gerasimova.

Additional information

Original Russian Text © Yu.V. Gerasimova, A.S. Oreshonkov, A.N. Vtyurin, A.A. Ivanenko, L.I. Isaenko, A.A. Ershov, E.I. Pogoreltsev, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 11, pp. 2215–2217.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gerasimova, Y.V., Oreshonkov, A.S., Vtyurin, A.N. et al. Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal. Phys. Solid State 55, 2331–2334 (2013). https://doi.org/10.1134/S1063783413110097

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783413110097

Keywords

Search

Navigation