Abstract
Results of the Raman spectroscopy analysis of a new composite material based on a thin polycrystalline LiF film containing gold nanoparticles are presented. The formation of spherical gold nanoparticles in the film has been confirmed by the X-ray structural analysis and observation of the optical plasmon resonance absorption spectrum with a maximum at 534 nm. The obtained composite layers have been subjected to annealing by ruby laser (λ = 694 nm) in the spectral region on a descending long-wavelength wing of the plasmon absorption band of gold nanoparticles. Raman spectroscopy has been applied for the first time to the investigation of the modification of the shape of gold nanoparticles in LiF during laser annealing. The experimental Raman spectra are compared with calculated modes of in-phase bending vibrations generated in gold nanoparticles.
Similar content being viewed by others
References
A. Courty, I. Lisiecki, and M. P. Pileni, J. Chem. Phys. 116, 8074 (2002).
B. Stephanidis, S. Adichtchev, S. Etienne, S. Migot, E. Duval, and A. Mermet, Phys. Rev. B: Condens. Matter 76, 121 404 (2007).
N. V. Kurbatova, M. F. Galyautdinov, E. I. Shtyrkov, V. I. Nuzhdin, and A. L. Stepanov, Phys. Solid State 52(6), 1255 (2010).
R. M. Montereali, T. Marolo, M. Montecchi, and E. Nichelatti, Nucl. Instrum. Methods Phys. Res., Sect. B 268, 2866 (2010).
G. Baldacchini, J. Lumin. 100, 333 (2002).
A. Sarychev and V. Shalaev, Electrodynamics of Metamaterials (World Scientific, New York, 2007).
V. K. Upadhyayula, Anal. Chim. Acta 715, 1 (2012).
A. I. Ryasnyanskiy, B. Palpant, S. Debrus, U. Pal, and A. L. Stepanov, Opt. Commun. 273, 538 (2007).
A. L. Stepanov, Tech. Phys. 49(2), 143 (2004).
A. L. Stepanov, Ion-Synthesis of Silver Nanoparticles and Their Optical Properties (Nova Science, New York, 2010).
N. A. Ivanov, S. S. Kolesnikov, V. P. Papernyi, Yu. N. Osin, and A. L. Stepanov, Tech. Phys. Lett. 37(10), 939 (2011).
U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters (Springer-Verlag, Berlin, 1995).
M. Fuiji, T. Nagareda, S. Nayashi, and K. Yamamoto, Phys. Rev. B: Condens. Matter 44, 6243 (1991).
M. Ferari, F. Gonella, M. Montagna, and C. Tosello, J. Appl. Phys. 79, 2055 (1996).
J. Jakcle, in Amorphous Solids, Ed. by W. Phillips (Springer-Verlag, Berlin, 1981), p. 54.
E. I. Shtyrkov, A. Klimovitskii, H. W. den Hartog, and D. I. Vainshtein, J. Phys.: Condens. Matter 14, 9053 (2002).
W. Hayes and R. Loudon, Scattering of Light by Crystals (Wiley, New York, 1978).
H. Poulet and J.-P. Mathieu, Spectres de vibration et symetrie des cristaux (Nova Science, New York, 1970) [in French].
A.L. Stepanov. in Encyclopedia of Laser Research, Ed. by Jillian R. McDonald (Nova Science, New York, 2012), Vol. 3, p. 27.
G. Seifert, M. Kaempfe, K.-J. Berg, and H. Graener, Appl. Phys. B 71, 795 (2000).
T. Gilson and P. Hendra, Laser Raman Spectroscopy (Academic, London, 1970; Mir, Moscow, 1973).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Kurbatova, M.F. Galyautdinov, N.A. Ivanov, S.S. Kolesnikov, V.L. Papernyi, Yu.N. Osin, A.L. Stepanov, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 9, pp. 1784–1787.
Rights and permissions
About this article
Cite this article
Kurbatova, N.V., Galyautdinov, M.F., Ivanov, N.A. et al. Raman spectroscopy of gold nanoparticles in polycrystalline LiF film. Phys. Solid State 55, 1899–1902 (2013). https://doi.org/10.1134/S1063783413090217
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783413090217