Abstract
A study has been made of the electrical conductivity of V6O11 single crystals over a broad range of temperatures covering the regions of the metal phase, metal-insulator phase transition, and insulator phase. It has been shown that the electrical conductivity of the metal phase correlates with the Mott limit of minimum conductivity. To explain the temperature dependence of the electrical conductivity of the V6O11 insulator phase, the theory of hopping conduction taking into account the effect of thermal vibration of atoms on the resonance integral has been invoked.
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H. Horiuchi, N. Morimoto, and M. Tokonami, J. Solid State Chem. 17, 407 (1976)
H. Horiuchi, M. Tokonami, N. Morimoto, K. Nagasawa, Y. Bando, and T. Takada, Mater. Res. Bull. 6, 833 (1971).
S. Kashi, K. Kosuge, and H. Okinaka, J. Solid State Chem. 6, 258 (1973).
S. Anderson and L. Jahnberg, Ark. Kemi 21, 413 (1964).
S. Nagata, P. H. Keesom, and S. P. Faile, Phys. Rev. B: Condens. Matter 20, 2886 (1979).
A. C. Gossard, F. J. Di Salvo, L. C. Erich, J. P. Remeika, H. Yasuoka, K. Kosuge, and S. Kachi, Phys. Rev. B: Solid State 10, 4178 (1974).
P. B. Allen, R. M. Wentscovitch, W. W. Schulz, and P. C. Canfield, Phys. Rev. B: Condens. Matter 48, 4359 (1993).
V. N. Andreev, F. A. Chudnovskii, and V. A. Klimov, JETP Lett. 60(9), 647 (1994).
E. J. Verwey, P. W. Haayman, and F. C. Romeijn, J. Chem. Phys. 15, 181 (1947).
V. N. Andreev and V. A. Klimov, Phys. Solid State 51(11), 2235 (2009).
V. N. Andreev and V. A. Klimov, Phys. Solid State 53(12), 2424 (2011).
U. Schwingenschogl, V. Eyert, and U. Eckern, Europhys. Lett. 61, 361 (2003).
H. Okinaka, K. Nagasawa, K. Kosuge, Y. Bando, S. Kachi, and T. Takada, J. Phys. Soc. Jpn. 29, 245 (1970).
V. N. Andreev, F. A. Chudnovskiy, J. M. Honig, and P. A. Metcalf, Phys. Rev. B: Condens. Matter 70, 235124 (2004).
V. V. Bryksin, Sov. Phys. JETP 73(5), 861 (1991).
C. M. Hurd, J. Phys. C: Solid State Phys. 18, 6484 (1985).
K. Nagasawa, Y. Bando, and T. Takada, Jpn. J. Appl. Phys. 8, 1262 (1969).
K. Nagasawa, Y. Bando, and T. Takada, J. Cryst. Growth 17, 143 (1972).
V. N. Andreev, V. A. Pikulin, and D. I. Frolov, Phys. Solid State 42(2), 330 (2000).
V. N. Andreev and F. A. Chudnovskii, Sov. Phys. Solid State 17(10), 1966 (1975).
N. F. Mott, Metal-Insulator Transitions (Tailor and Francis, London, 1974).
A. Erragh, G. Villeneuve, and P. Hagenmuller, Mater. Res. Bull. 19, 355 (1984).
A. G. Aronov, D. N. Mirlin, I. I. Reshina, and F. A. Chudnovskii, Sov. Phys. Solid State 19(1), 110 (1977).
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Original Russian Text © V.N. Andreev, V.A. Klimov, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 9, pp. 1717–1722.
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Andreev, V.N., Klimov, V.A. Specific features of the electrical conductivity of V6O11 . Phys. Solid State 55, 1829–1834 (2013). https://doi.org/10.1134/S1063783413090047
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DOI: https://doi.org/10.1134/S1063783413090047