Abstract
Photogeneration of electric charge carriers at high strengths of the external electric field and the temperature of transition to the viscous-flow state (T visc) of thin PEPC-C60 composite films obtained by casting from a toluene solution have been studied. The rheology of the composite films has been investigated by the nondestructive optical method. The consistent correlated change in the values of T visc and the effective temperature in the expression for the photogeneration quantum yield (T 0) in the Meltz representation with variations in the C60 concentration has been established. The difference between T visc and T 0 in thin composite films does not exceed 2–3% of T visc (T 0).
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G. Dennler, N. S. Sariciftci, and C. J. Brabec, Conjugated Polymer-Based Organic Solar Cells, Semiconducting Polymers: Chemistry, Physics and Engineering, Ed. by G. Hadziioannou and G. G. Hunray, 2nd ed., (Wiley, Weinheim, 2006), Vol. 1.
E. L. Aleksandrova, Semiconductors 38(10), 1115 (2004).
S. G. Tikhodeev and N. A. Gippius, Phys.—Usp. 52(9), 945 (2009).
G. G. Vlaikov, M. Yu. Barabash, M. A. Zabolotnyi, D. O. Grin’ko, Yu. M. Barabash, and L. Yu. Kunitskaya, Formation of Nanostructures by Templating Synthesis (Technical Center of National Academy of Sciences of Ukraine, Kyiv, 2010) [in Russian].
M. Pope and C. E. Swenberg, Annu. Rev. Chem. 35, 613 (1984).
E. Silin’sh, M. Kurik, and V. Chapek, Electronic Processes in Organic Molecular Crystals (Zinatne, Riga, 1988) [in Russian].
N. G. Kuvshinskii, N. A. Davidenko, and P. M. Komko, Physics of Amorphous Molecular Semiconductors (Lybed’, Kyiv, 1994) [in Russian].
K. Falkowski, W. Stampor, P. Grygiel, and W. Tomaszewicz, Chem. Phys. 392(1), 122 (2012).
N. P. Kulish, Yu. M. Barabash, M. A. Zabolotny, D. A. Grin’ko, O. P. Dmitrenko, and E. S. Kobus, Phys. Solid State 50(7), 1374 (2008).
V. Gulbinas, D. Hertel, A. Yartsev, and V. Sundström, Phys. Rev. B 76, 235203 (2007).
V. A. Kolesnikov, V. S. Saenko, A. P. Tyutnev, and E. D. Pozhidaev, Polym. Sci., Ser. A 48(1), 46 (2006).
Ch. Chong, W. Fan, G. Hongwei, Sh. Wei, and W. Mingtaw. Nanoscale Res. Lett. 6(1), 350 (2011).
A. Yu. Grosberg and A. R. Khokhlov, Statistical Physics of Macromolecules (Nauka, Moscow, 1989; American Institute of Physics, New York, 2002).
T. G. Elizarova, Mathematical Models and Numerical Methods in Dynamics of Liquid and Gas (Department of Physics, Moscow State University, Moscow, 2005), p. 224 [in Russian].
L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 6: Fluid Mechanics (IFML, Moscow, 1986; Butterworth-Heinemann, Oxford, 1987).
N. A. Davydenko, N. A. Derevjanko, A. A. Ischenko, G. P. Olkhovyk, P. S. Smertenko, and L. I. Fenenko, Phys. Chem. Solid State 2(4), 623 (2001).
N. G. Kuvshinskii, N. G. Nakhodkin, M. A. Zabolotnyi, and V. M. Komko, Ukr. Fiz. Zh. 28,(11), 1729 (1983).
Yu. M. Barabash, M. S. Borodkina, I. A. Malakhova, and N. A. Marshak, Fundam. Osn. Opt. Pamyati Sredy, No. 15, 9 (1984).
Y. F. Budd, J. Appl. Phys. 36(5), 1613 (1965).
N. A. Davydenko, Yu. P. Get’manchuk, M. A. Zabolotnyi, T. G. Zabolotnaya, L. P. Linets, E. V. Mokrinskaya, V. A. Pavlov, S. L. Studzinskii, and N. G. Chuprina, High Energy Chem. 40(6), 410 (2006).
R. Collier, C. Burckhardt, and L. Lin, Optical Holography (Academic, New York, 1971; Mir, Moscow, 1973).
P. A. Rebinder, Kolloidn. Zh. 8(3), 157 (1946).
J. Berni, W. Older, and A. W. Edward, in Physics Abroad, Ser. A, Ed. by I. A. Fedoseeva (Mir, Moscow, 1986) [in Russian].
G. M. Bartenev and Yu. V. Zelenev, Physics and Mechanics of Polymers (Vysshaya Shkola, Moscow, 1983) [in Russian].
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Original Russian Text © M.A. Zabolotny, Yu.M. Barabash, O.P. Dmitrenko, N.P. Kulish, N.A. Davidenko, S.L. Studzinskii, A.P. Olasyuk, A.V. Demchenko, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 8, pp. 1626–1632.
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Zabolotny, M.A., Barabash, Y.M., Dmitrenko, O.P. et al. On the mechanisms of photogeneration of charge carriers in PEPC-C60 composites. Phys. Solid State 55, 1739–1746 (2013). https://doi.org/10.1134/S106378341308026X
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DOI: https://doi.org/10.1134/S106378341308026X