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Nonisothermal nucleation in the CuCl solid solution in glass: Formation of two distributions of nanoparticles of a new phase in the solid solution with a negative jump of the nucleation temperature

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Abstract

The processes of nonisothermal nucleation in the CuCl solid solution in glass with a negative jump of the nucleation temperature have been investigated using optical spectroscopy and exciton-thermal analysis. Two distributions of CuCl nanoparticles differing in the average radii R (2.3 and 14.0 nm) have been obtained for the temperature drop from T 1 = 700°C to T 2 = 500°C. The formation of two distributions of CuCl particles has been numerically simulated and the agreement between the experimental and calculated radius distributions of CuCl particles has been obtained.

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References

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Authors and Affiliations

  1. St. Petersburg State Technological University of Plant Polymers, ul. Ivana Chernykh 4, St. Petersburg, 198095, Russia

    V. I. Leiman, P. M. Valov, V. M. Maksimov, O. Yu. Derkacheva & E. S. Markov

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  1. V. I. Leiman
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  2. P. M. Valov
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  3. V. M. Maksimov
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  4. O. Yu. Derkacheva
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  5. E. S. Markov
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Correspondence to V. I. Leiman.

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Original Russian Text © V.I. Leiman, P.M. Valov, V.M. Maksimov, O.Yu. Derkacheva, E.S. Markov, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 6, pp. 1167–1170.

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Leiman, V.I., Valov, P.M., Maksimov, V.M. et al. Nonisothermal nucleation in the CuCl solid solution in glass: Formation of two distributions of nanoparticles of a new phase in the solid solution with a negative jump of the nucleation temperature. Phys. Solid State 55, 1258–1261 (2013). https://doi.org/10.1134/S106378341306022X

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  • DOI: https://doi.org/10.1134/S106378341306022X

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