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Physics of the Solid State

, Volume 55, Issue 6, pp 1148–1155 | Cite as

Magnetic properties and surface morphology of layered In2Se3 crystals intercalated with cobalt

  • A. P. Bakhtinov
  • V. B. Boledzyuk
  • Z. D. Kovalyuk
  • Z. R. KudrynskyiEmail author
  • O. S. Lytvyn
  • A. D. Shevchenko
Semiconductors

Abstract

The magnetic properties of layered Co x In2Se3 crystals electrochemically intercalated with cobalt in an external magnetic field and without a magnetic field and the morphology of the van der Waals surfaces of layers of these crystals have been investigated. It has been found that the ferromagnetic ordering at room temperature is observed only for Co x In2Se3 crystals intercalated in an external magnetic field. These crystals are nanocomposite materials that consist of a layered matrix and arrays of nanorings and nanowires formed from Co nanocrystals on the van der Waals surfaces of the In2Se3 layers. Cobalt nanocrystals in Co x In2Se3 crystals have a pyramidal equilibrium shape, which is characteristic of the face-centered cubic crystal structure, and their geometrical sizes are of the order of a few nanometers. The specific features of self-organization of cobalt magnetic nanostructures on the van der Waals surfaces of layered semiconductor crystals during their electrolytic intercalation in a magnetic field and the magnetic properties of these structures have been considered.

Keywords

External Magnetic Field Layered Crystal SnSe Nanopar Ticles Indium Selenide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • A. P. Bakhtinov
    • 1
  • V. B. Boledzyuk
    • 1
  • Z. D. Kovalyuk
    • 1
  • Z. R. Kudrynskyi
    • 1
    Email author
  • O. S. Lytvyn
    • 2
  • A. D. Shevchenko
    • 3
  1. 1.Chernivtsi DepartmentFrantsevich Institute for Problems of Materials ScienceChernivtsiUkraine
  2. 2.Lashkaryov Institute of Semiconductor PhysicsNational Academy of Sciences of UkraineKyivUkraine
  3. 3.Kurdyumov Institute for Metal PhysicsNational Academy of Sciences of UkraineKyivUkraine

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