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Synthesis and electrochemical properties of Li8 − x Zr1 − x Nb x O6 solid solutions

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Abstract

New lithium-conducting solid solutions based on lithium orthozirconate have been synthesized by mutual doping of the related structures Li8ZrO6 and Li7NbO6. The main factor determining the increase in the electrical conductivity of the Li8 − x Zr1 − x Nb x O6 solid solutions is the formation of lithium vacancies in the tetrahedral and octahedral layers. The practical stability of the Li8 − x Zr1 − x Nb x O6 ceramics to metallic lithium has been studied.

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Authors and Affiliations

  1. Institute of High Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences, ul. Sofii Kovalevskoi 22, Yekaterinburg, 620219, Russia

    M. I. Pantyukhina, M. S. Shchelkanova & S. V. Plaksin

Authors
  1. M. I. Pantyukhina
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  2. M. S. Shchelkanova
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  3. S. V. Plaksin
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Correspondence to M. I. Pantyukhina.

Additional information

Original Russian Text © M.I. Pantyukhina, M.S. Shchelkanova, S.V. Plaksin, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 4, pp. 650–651.

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Pantyukhina, M.I., Shchelkanova, M.S. & Plaksin, S.V. Synthesis and electrochemical properties of Li8 − x Zr1 − x Nb x O6 solid solutions. Phys. Solid State 55, 707–709 (2013). https://doi.org/10.1134/S1063783413040227

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  • DOI: https://doi.org/10.1134/S1063783413040227

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