Abstract
The lattice dynamics and energies of phases related to antiferrodistorsive and ferroelectric distortions of bulk crystals and thin films of the SrZrO3 crystal have been calculated within the framework of the ab initio model of an ionic crystal. In the case of a bulk crystal, it has been found that the most energetically favorable phases are related to antiferrodistorsive lattice distortions. Ferroelectricity in the SrZrO3 crystal is suppressed by structural lattice distortions. In the case of thin films, it has been found that the ferroelectric instability is retained after the “rotation” of the oxygen octahedron and the film remains polar both in the case of a free surface and with the inclusion of the SrTiO3 substrate in the calculation. The spontaneous polarization of thin films of different thicknesses in the ferroelectric phase has been calculated.
Similar content being viewed by others
References
E. Mete, R. Shaltaf, and S. Ellialtiouglu, Phys. Rev. B: Condens. Matter 68, 035119 (2003).
D. de Ligny and P. Richet, Phys. Rev. B: Condens. Matter 53(6), 3013 (1996).
C. J. Howard, K. S. Knight, B. J. Kennedy, and E. H. Kisi, J. Phys.: Condens. Matter 12, 677 (2000).
C. Chen, W. Zhu, T. Yu, X. Chen, and X. Yao, Appl. Surf. Sci. 211, 244 (2003).
T. Higuchi, T. Tsukamoto, S. Yamaguchi, N. Sata, K. Hiramoto, M. Ishigame, and S. Shin, Jpn. J. Appl. Phys. 41, 6440 (2002).
R. Vali, J. Phys. Chem. Solids 69(4), 876 (2008).
S. Davitadze, I. Shnaidshtein, F. Fadeev, B. Strukov, S. Shulman, B. Noheda, and A. H. G. Vlooswijk, Ferroelectrics 397, 102 (2010).
E. G. Maksimov, V. I. Zinenko, and N. G. Zamkova, Phys.—Usp. 47(11), 1075 (2004).
R. I. Eglitis and M. Rohlfing, J. Phys.: Condens. Matter 22, 415901 (2010).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.S. Zhandun, V.I. Zinenko, 2012, published in Fizika Tverdogo Tela, 2012, Vol. 54, No. 7, pp. 1309–1316.
Rights and permissions
About this article
Cite this article
Zhandun, V.S., Zinenko, V.I. Lattice dynamics and the ferroelectric and antiferrodistorsive instabilities in a bulk crystal and thin films of SrZrO3 . Phys. Solid State 54, 1388–1396 (2012). https://doi.org/10.1134/S1063783412070359
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783412070359