Skip to main content
SpringerLink
Log in

Fast ionic transport in Ag x TiS2

  • Defects and Impurity Centers, Dislocations, and Physics of Strength
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The enthalpy of the subsystem of silver ions in the intercalation compounds Ag x TiS2 has been calculated from the electrochemically measured thermodynamic functions of the silver subsystem. The ionic conductivity and the coupled chemical diffusion coefficients for silver in the intercalation compound have been measured. The activation energy for diffusion of silver ions is determined and the obtained value is interpreted from analyzing the concentration dependence of the enthalpy of the ionic subsystem. The conclusion has been drawn that the high diffusion mobility is associated with the competition between the covalent and elastic interactions, which decreases the activation energy for diffusion of ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. Ya. Gurevich and Yu. I. Kharkats, Superionic Conductors (Nauka, Moscow, 1992) [in Russian].

    Google Scholar 

  2. T. Hibma, in Intercalation Chemistry, Ed. by M. S. Wittingham and A. J. Jacobsen (Academic, London, 1982), p. 285.

    Google Scholar 

  3. A. N. Titov and S. G. Titova, Fiz. Tverd. Tela (St. Petersburg) 37(2), 567 (1995) [Phys. Solid State 37 (2), 310 (1995)].

    Google Scholar 

  4. V. G. Pleshchev, A. N. Titov, and A. V. Kuranov, Fiz. Tverd. Tela (St. Petersburg) 39(9), 1618 (1997) [Phys. Solid State 39 (9), 1442 (1997)].

    Google Scholar 

  5. C. Wagner, Thermodynamics of Alloys (Addison-Wesley, Reading, MA, United States, 1952; Metallurgizdat, Moscow, 1957).

    Google Scholar 

  6. A. N. Titov and Kh. M. Bikkin, Fiz. Tverd. Tela (St. Petersburg) 34(11), 3593 (1992) [Sov. Phys. Solid State 34 (11), 1924 (1992)].

    Google Scholar 

  7. A. N. Titov and Kh. M. Bikkin, Fiz. Tverd. Tela (Leningrad) 33(6), 1876 (1991) [Sov. Phys. Solid State 33 (6), 1054 (1991)].

    Google Scholar 

  8. I. Yokota, J. Phys. Soc. Jpn. 8(5), 595 (1953).

    Article  ADS  Google Scholar 

  9. G. A. Gerardes, H. Roede, R. J. Haange, B. A. Boukamp, and A. G. Wiegers, Synth. Met. 10, 51 (1984/1985).

    Article  Google Scholar 

  10. V. N. Chebotin and M. V. Perfil’ev, Electrochemistry of Solid Electrolytes (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  11. Yu. Ya. Gurevich and Yu. I. Kharkats, Usp. Fiz. Nauk 136(4), 693 (1982) [Sov. Phys.—Usp. 25 (4), 257 (1982)].

    Google Scholar 

  12. J. R. Dahn, D. C. Dahn, and R. R. Haering, Solid State Commun. 42(3), 179 (1982).

    Article  ADS  Google Scholar 

  13. K. K. Bardhan, G. Kirczenow, G. Jackle, and J. C. Irwin, Phys. Rev. B: Condens. Matter 33, 4149 (1986).

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Metal Physics, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoĭ 18, Yekaterinburg, 620219, Russia

    A. N. Titov

  2. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    A. N. Titov

Authors
  1. A. N. Titov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Titov.

Additional information

Original Russian Text © A.N. Titov, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 4, pp. 675–680.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Titov, A.N. Fast ionic transport in Ag x TiS2 . Phys. Solid State 51, 714–720 (2009). https://doi.org/10.1134/S1063783409040106

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783409040106

PACS numbers

Search

Navigation