Skip to main content
Log in

Magnetic and electrical properties of cation-substituted sulfides Me x Mn1 − x S (Me = Co, Gd)

  • Semiconductors and Dielectrics
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The temperature dependences of the specific magnetization σ and the electrical resistivity ρ of Me x Mn1 − x S single crystals (Me= Co, Gd; x= 0.05) have been studied in the temperature range 80 K < T < 1000 K. The samples under study have revealed the presence of a spontaneous magnetic moment below the Néel temperature (T N) and ferromagnetic clusters in Gd0.05Mn0.95S in the temperature range 146 K < T < 680 K. Substitution of gadolinium for manganese initiates a transition from p-type to n-type conduction. The change in the conduction type is accompanied by an increase in the electrical resistivity at 300 K by approximately one order of magnitude and, accordingly, by a decrease in the activation energy. The magnetic and electrical properties of the crystals under study have been interpreted in terms of the cluster model with temperature-dependent ferromagnetic exchange and an electron localized in this cluster.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. V. Vedyaev, Usp. Fiz. Nauk 172(12), 1458 (2002) [Phys.-Usp. 45 (12), 1296 (2002)].

    Article  Google Scholar 

  2. A. S. Borukhovich, Physics of Materials and Structures of Superconducting and Semiconducting Spin Electronics (Ural Division of the Russian Academy of Sciences, Yekaterinburg, 2004) [in Russian].

    Google Scholar 

  3. N. F. Mott, Metal—Insulator Transitions (Taylor and Francis, London, 1974; Nauka, Moscow, 1979).

    Google Scholar 

  4. E. L. Nagaev, Usp. Fiz. Nauk 166(8), 833 (1996) [Phys.-Usp. 39 (8), 781 (1996)].

    Google Scholar 

  5. Y. Zhaorong, T. Shun, C. Zhiwen, and Y. Zhang, Phys. Rev. B: Condens. Matter 62, 13872 (2000).

    Google Scholar 

  6. N. I. Solin, V. V. Ustinov, and S. V. Naumov, Fiz. Tverd. Tela (St. Petersburg) 50(5), 864 (2008) [Phys. Solid State 50 (5), 901 (2008)].

    Google Scholar 

  7. V. A. Sanina, E. I. Golovenchits, and V. G. Zalesskiĭ, Fiz. Tverd. Tela (St. Petersburg) 50(5), 883 (2008) [Phys. Solid State 50 (5), 922 (2008)].

    Google Scholar 

  8. G. A. Petrakovskiĭ, L. I. Ryabinkina, G. M. Abramova, A. D. Balaev, D. A. Balaev, and A. F. Bovina, Pis’ma Zh. Éksp. Teor. Fiz. 72(2), 99 (2000) [JETP Lett. 72 (2), 70 (2000)].

    Google Scholar 

  9. L. I. Ryabinkina, O. B. Romanova, G. A. Petrakovskii, N. I. Kiselev, G. I. Makovetskii, K. I. Yanushkevich, J. Schefer, A. I. Galyas, O. F. Demidenko, A. F. Bovina, and E. A. Mal’tzeva, Phys. Met. Metallogr. 99(Suppl. 1), S77 (2005).

    Google Scholar 

  10. L. I. Ryabinkina, O. B. Romanova, and S. S. Aplesnin, Izv. Akad. Nauk, Ser. Fiz. 72, 1115 (2008).

    Google Scholar 

  11. S. S. Aplesnin, L. I. Ryabinkina, O. B. Romanova, D. A. Velikanov, A. D. Balaev, D. A. Balaev, K. I. Yanushkevich, A. I. Galyas, O. F. Demidenko, and O. N. Bandurina, Zh. Éksp. Teor. Fiz. 133(4), 875 (2008) [JETP 106 (4), 765 (2008)].

    Google Scholar 

  12. J. B. Goodenough, Magnetism and the Chemical Bond (Wiley, New York, 1963; Metallurgiya, Moscow, 1968).

    Google Scholar 

  13. S. S. Aplesnin, L. I. Ryabinkina, G. M. Abramova, O. B. Romanova, N. I. Kiselev, and A. F. Bovina, Fiz. Tverd. Tela (St. Petersburg) 46(11), 2000 (2004) [Phys. Solid State 46 (11), 2067 (2004)].

    Google Scholar 

  14. R. Tappero, P. Wolfers, and A. Lichanot, Chem. Phys. Lett. 335, 449 (2001).

    Article  ADS  Google Scholar 

  15. H. H. Heikens, C. F. van Bruggen, and C. Haas, J. Phys. Chem. Solids 39, 833 (1978).

    Article  ADS  Google Scholar 

  16. S. S. Aplesnin, L. I. Ryabinkina, G. M. Abramova, O. B. Romanova, A. M. Vorotynov, D. A. Velikanov, N. I. Kiselev, and A. D. Balaev, Phys. Rev. B: Condens. Matter 71, 125 204 (2005).

    Google Scholar 

  17. É. L. Nagaev, Physics of Magnetic Semiconductors (Nauka, Moscow, 1979; Mir, Moscow, 1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. B. Romanova.

Additional information

Original Russian Text © S.S. Aplesnin, L.I. Ryabinkina, O.B. Romanova, V.V. Sokolov, A.Yu. Pichugin, A.I. Galyas, O.F. Demidenko, G.I. Makovetskiĭ, K.I. Yanushkevich, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 4, pp. 661–664.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aplesnin, S.S., Ryabinkina, L.I., Romanova, O.B. et al. Magnetic and electrical properties of cation-substituted sulfides Me x Mn1 − x S (Me = Co, Gd). Phys. Solid State 51, 698–701 (2009). https://doi.org/10.1134/S1063783409040076

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783409040076

PACS numbers

Navigation