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Micro-Raman response and phonon oscillator parameters in solid solutions Pb1 − x Ca x TiO3 (0.40 < x < 0.62)

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Abstract

The temperature (295 K < T < 650 K) investigations of the polarized Raman spectra measured for a single-crystal sample of the Pb0.54Ca0.46TiO3 solid solution in the frequency range 10 < ν < 1200 cm−1 have established the existence of at least one specific temperature (T c ≈ 392 K) at which the oscillator parameters of phonon modes exhibit noticeable anomalies. Similar phenomena are observed in solutions with 0.4 < x < 0.5. A sharp increase in the intensity of the spectral lines corresponding to polarization waves at temperatures immediately below T c suggests a transformation of Pb1 −x Ca x TiO3 (0.4 < x < 0.5) into a polar state, which does not exist for x > 0.5.

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Authors and Affiliations

  1. Southern Federal University, Bol’shaya Sadovaya ul. 105, Rostov-on-Don, 344006, Russia

    A. N. Chabanyuk, V. I. Torgashev & Yu. I. Yuzyuk

  2. Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    V. V. Lemanov

  3. CEMHTI—Conditions Extrêmes et Matériaux: Haute Température et Irradiation UPR3079 CNRS, 1D avenue de la Recherche Scientifique, Orléans, Cedex 2, 45071, France

    P. Simon

Authors
  1. A. N. Chabanyuk
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  2. V. I. Torgashev
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  3. Yu. I. Yuzyuk
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  4. V. V. Lemanov
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  5. P. Simon
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Correspondence to V. I. Torgashev.

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Original Russian Text © A.N. Chabanyuk, V.I. Torgashev, Yu.I. Yuzyuk, V.V. Lemanov, P. Simon, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 1, pp. 155–163.

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Chabanyuk, A.N., Torgashev, V.I., Yuzyuk, Y.I. et al. Micro-Raman response and phonon oscillator parameters in solid solutions Pb1 − x Ca x TiO3 (0.40 < x < 0.62). Phys. Solid State 51, 165–173 (2009). https://doi.org/10.1134/S1063783409010211

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  • DOI: https://doi.org/10.1134/S1063783409010211

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