Abstract
A study has been made of the effect of a dc electric field (0 < E < 4 kV/cm) on the optical transmittance of single-crystal compounds PbMg1/3Nb2/3O3-xPbTiO3 (PMN-xPT) located at the boundaries of the morphotropic region (x = 32.0 and 36.5%) and directly at the center of the morphotropic region (x = 35%). It is shown that, at temperatures close to the morphotropic phase transition point, the electric field induces two phase transitions in PMN-32PT and PMN-35PT crystals and only one phase transition in PMN-36.5PT. The tetragonal (T) phase induced in all three compounds remains stable after the electric field is removed only in crystals with x = 35.0 and 36.5%, whereas the T phase is metastable and transforms into the monoclinic M c phase after the field is switched off in the PMN-32PT crystals lying at the boundary of the morphotropic region on the rhombohedral side. It is found that the electric-field-induced intermediate phase M c in PMN-35PT is inhomogeneous and that M c transforms into the tetragonal phase in a continuous transition. It is suggested that only the presence of a third orthorhombic phase can account for the continuous character of the transition between the M c and T phases in PMN-35PT crystals. The results obtained are interpreted in terms of the Devonshire theory for strongly anharmonic crystals. The E-T phase diagrams are constructed for all the crystals.
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Original Russian Text © L.S. Kamzina, H. Luo, J. Xu, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 10, pp. 1861–1865.
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Kamzina, L.S., Luo, H. & Xu, J. Optical investigations of structural phase transformations in PbMg1/3Nb2/3O3-xPbTiO3 single crystals located at the morphotropic phase boundary. Phys. Solid State 50, 1940–1945 (2008). https://doi.org/10.1134/S1063783408100259
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DOI: https://doi.org/10.1134/S1063783408100259