Abstract
The location of the energy levels of rare-earth (RE) elements in the energy band diagram of BaF2 and CdF2 crystals is determined. The role of RE 3+ and RE 2+ ions in the capture of charge carriers, luminescence, and the formation of radiation defects is evaluated. It is shown that the substantial difference in the luminescence properties of BaF2: RE and CdF2: RE is associated with the location of the excited energy levels in the band diagram of the crystals.
Similar content being viewed by others
References
C. W. Thiel, H. Cruguel, H. Wu, Y. Sun, G. J. Lapeyre, R. L. Cone, R. W. Equall, and R. M. Macfarlane, Phys. Rev. B: Condens. Matter 64, 085 107 (2001).
P. Dorenbos, J. Lumin. 108, 301 (2004).
P. Dorenbos, J. Phys.: Condens. Matter 15, 8417 (2003).
P. A. Rodnyi, Radiat. Meas. 33, 605 (2001).
M. Kobayashi and M. Ishii, Nucl. Instrum. Methods Phys. Res., Sect. B 82, 85 (1992).
S. Ren, G. Chen, P. Zhang, and Y. Zheng, Mater. Res. Soc. Symp. Proc. 348, 435 (1994).
E. Auffray, I. Dafinei, P. Lecoq, and M. Schneegans, Mater. Res. Soc. Symp. Proc. 348, 111 (1994).
S. I. Kuptsov, A. S. Solov’ev, V. G. Vasil’chenko, A. A. Bistrova, I. I. Buchinskaya, E. A. Krivandina, B. P. Sobolev, Z. I. Zhmurova, Yu. A. Krechko, Yu. D. Motin, and A. V. Antipov, Nucl. Instrum. Methods Phys. Res., Sect. B 103, 323 (1995).
P. A. Rondyi, M. A. Terekhin, and E. N. Mel’chakov, J. Lumin. 47, 281 (1991).
P. A. Rondy, G. B. Struganyuk, C. W. E. van Eijk, and A. S. Voloshinovskii, Phys. Rev. B: Condens. Matter 72, 195 112 (2005).
P. A. Rodnyĭ, A. Kh. Khadro, A. S. Voloshinovskiĭ, and G. B. Stryganyuk, Opt. Spektrosk. 103(4), 589 (2007) [Opt. Spectrosc. 103 (4), 568 (2007)].
B. Moine, C. Pedrini, and B. Courtois, J. Lumin. 50, 31 (1991).
C. Pedrini, D. S. McClure, and C. H. Anderson, J. Chem. Phys. 70, 4960 (1979).
C. Pedrini, F. Rogemond, and D. S. McClure, J. Appl. Phys. 59, 1196 (1986).
E. Radzhabov, Nucl. Instrum. Methods Phys. Res., Sect. A 486, 458 (2002).
D. Hommel and J. M. Langer, J. Lumin. 18–19, 281 (1979).
S. Benci and G. Schianchi, J. Lumin. 11, 349 (1976).
H. Przybylinska, M. Goldewski, and D. Hommel, Phys. Rev. B: Condens. Matter 46, 7395 (1992).
A. V. Sidorenko, P. Dorenbos, A. J. J. Bos, C. W. E. van Eijk, and P. A. Rodnyi, J. Phys.: Condens. Matter 18, 4503 (2006).
J. D. Kingsley and J. S. Prener, Phys. Rev. Lett. 8, 315 (1962).
V. G. Vasil’chenko and M. Kobayashi, in Multicomponent Crystals Based on Heavy Metal Fluorides for Radiation Detectors, Ed. by B. P. Sobolev (Institut D’estudis Catalans, Barcelona, 1994), Chap. 6, p. 177.
E. van der Kolk and P. Dorenbos, Chem. Matter. 18, 3458 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © P.A. Rodnyĭ, I.V. Khodyuk, G.B. Stryganyuk, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 9, pp. 1578–1581.
Rights and permissions
About this article
Cite this article
Rodnyĭ, P.A., Khodyuk, I.V. & Stryganyuk, G.B. Location of the energy levels of the rare-earth ions in BaF2 and CdF2 . Phys. Solid State 50, 1639–1643 (2008). https://doi.org/10.1134/S1063783408090072
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063783408090072