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Luminescence properties of the CsSnBr3 phase in metastable Cs4SnBr6

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Abstract

Crystalline materials of the compositions Cs4SnBr6, CsSnBr3, and CsBr-Sn (0.1 mol %) are investigated using x-ray diffraction and luminescent methods. The formation of the CsSnBr3 phase is found to occur in metastable Cs4SnBr6 and CsBr-Sn. It is established that the CsSnBr3 crystalline phase in the Cs4SnBr6 metastable phase is a more stable compound as compared to the CsSnBr3 bulk crystal, which undergoes oxidation and hydration in air.

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Authors and Affiliations

  1. Ivan Franko National University of Lviv, Universitetskaya ul. 1, Lviv, 79000, Ukraine

    S. V. Myagkota, P. V. Savchin, A. S. Voloshinovskiĭ, T. M. Demkiv, Ya. V. Boĭko, R. S. Vus & L. S. Demkiv

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  1. S. V. Myagkota
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  2. P. V. Savchin
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  3. A. S. Voloshinovskiĭ
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  4. T. M. Demkiv
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  5. Ya. V. Boĭko
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  6. R. S. Vus
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  7. L. S. Demkiv
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Correspondence to T. M. Demkiv.

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Original Russian Text © S.V. Myagkota, P.V. Savchin, A.S. Voloshinovskiĭ, T.M. Demkiv, Ya.V. Boĭko, R.S. Vus, L.S. Demkiv, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 8, pp. 1416–1419.

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Myagkota, S.V., Savchin, P.V., Voloshinovskiĭ, A.S. et al. Luminescence properties of the CsSnBr3 phase in metastable Cs4SnBr6 . Phys. Solid State 50, 1473–1476 (2008). https://doi.org/10.1134/S1063783408080143

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  • DOI: https://doi.org/10.1134/S1063783408080143

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