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Kinetics of thermalization of electric charge carriers in organic molecular semiconductors in strong electric fields

  • Polymers and Liquid Crystals
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Abstract

The kinetics of photogeneration of electric charge carriers in organic molecular semiconductors in strong electric fields is investigated within a theoretical model that includes the diffusion-drift mechanism of motion of electric charge carriers. In the framework of the proposed model, it is established that the time dependence of the probability of dissociation of a geminal pair exhibits an exponential behavior. The time constant strongly depends on the electric charge carrier hopping distance and the external electric field strength in accordance with the experimental data.

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References

  1. E. L. Aleksandrova, Fiz. Tekh. Poluprovodn. (St. Petersburg) 38(10), 1153 (2004) [Semiconductors 38 (10), 1115 (2004)].

    Google Scholar 

  2. M. Pope and C. E. Swenberg, Annu. Rev. Phys. Chem. 35, 613 (1984).

    Article  Google Scholar 

  3. E. A. Silin’sh, V. A. Kolesnikov, I. Ya. Muzikante, D. R. Balode, and A. K. Gaĭlis, Izv. Akad. Nauk Latv. SSR, No. 5, 15 (1981).

  4. N. G. Kuvshinskiĭ, N. A. Davidenko, and V. M. Komko, Physics of Amorphous Molecular Semiconductors (Lybed’, Kiev, 1994) [in Russian].

    Google Scholar 

  5. E. A. Silinch, in Proceedings of the 11th Molecular Crystal Symposium, Lugano, Switzerland, 1985 (Lugano, 1985).

  6. N. Tsutsumi, M. Yamamoto, and Y. Nishijima, Polymer 29, 1655 (1988).

    Article  Google Scholar 

  7. É. A. Silin’sh, M. V. Kurik, and V. Chapek, Electronic Processes in Organic Molecular Crystals (Zinate, Riga, 1988) [in Russian].

    Google Scholar 

  8. N. A. Davidenko, N. A. Derevyanko, M. A. Zabolotny, A. A. Ishchenko, N. G. Kuvshinsky, and S. I. Studzinsky, High Energy Chem. 39, 158 (2005).

    Article  Google Scholar 

  9. Y. Barabash, M. Zabolotny, T. Zabolotna, and N. Sokolov, Proc. SPIE—Int. Soc. Opt. Eng. 6254, 217 (2006).

    Google Scholar 

  10. N. G. Kuvshinskiĭ, N. G. Nakhodkin, M. A. Zabolotnyĭ, V. M. Komko, and N. G. Chuprin, Ukr. Fiz. Zh. 28, 1729 (1983).

    Google Scholar 

  11. V. A. Gritsenko and V. A. Rzhanov, Zh. Tekh. Fiz. 46(10), 2155 (1976) [Sov. Phys. Tech. Phys. 21 (10), 1263 (1976)].

    Google Scholar 

  12. A. Siddiqui, J. Phys. C: Solid State Phys. 17, 683 (1984).

    Article  ADS  Google Scholar 

  13. N. A. Davidenko, M. A. Zabolotny, N. G. Kuvshinsky, and A. A. Ishchenko, Proc. SPIE—Int. Soc. Opt. Eng. 5507, 164 (2004).

    ADS  Google Scholar 

  14. Ya. B. Zel’dovich and A. D. Myshkis, Elements of Mathematical Physics (Nauka, Moscow, 1973) [in Russian].

    Google Scholar 

  15. L. Kulikovsky, D. Neher, E. Mecher, and K. Meerholz, Phys. Rev. B: Condens. Matter 69, 125215 (2004).

    Google Scholar 

  16. G. Winiarz Jeffry, F. Ghebremichael, Thomas Jayan, Meredith Gerald, and Peyghambarian Nasser, Opt. Express 12, 2518 (2004).

    Google Scholar 

  17. V. I. Gol’danskiĭ, L. I. Trakhtenberg, and V. N. Flerov, Tunneling Phenomena in Chemical Physics (Nauka, Moscow, 1986), p. 294 [in Russian].

    Google Scholar 

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Correspondence to E. S. Kobus.

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Original Russian Text © N.P. Kulish, Yu.M. Barabash, M.A. Zabolotny, D.A. Grin’ko, O.P. Dmitrenko, E.S. Kobus, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 7, pp. 1321–1326.

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Kulish, N.P., Barabash, Y.M., Zabolotny, M.A. et al. Kinetics of thermalization of electric charge carriers in organic molecular semiconductors in strong electric fields. Phys. Solid State 50, 1374–1380 (2008). https://doi.org/10.1134/S1063783408070305

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  • DOI: https://doi.org/10.1134/S1063783408070305

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