Abstract
The recombination of intrinsic point defects in dislocation-free silicon single crystals is investigated. It is established experimentally and confirmed by thermodynamic calculations that this process in the vicinity of the crystallization front is hindered by the recombination barrier. The recombination parameters (such as the recombination barrier height, the recombination time, and the recombination factor) for the model describing the dynamics of point defects at low and high temperatures are evaluated in terms of the heterogeneous mechanism of nucleation and transformation of grown-in microdefects. It is confirmed that the decomposition of a supersaturated solid solution of point defects can occur according to two mechanisms, namely, the vacancy and interstitial mechanisms. Vacancies and intrinsic interstitial silicon atoms find sinks in the form of oxygen and carbon background impurities. It is demonstrated that the formation of “intrinsic-point-defect-impurity” pairs is a dominant process in the vicinity of the melting temperature.
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R. A. Brown, D. Maroudas, and T. Sinno, J. Cryst. Growth 137, 12 (1994).
T. Sinno, R. A. Brown, W. von Ammon, and E. Dornberger, J. Electrochem. Soc. 145, 302 (1998).
T. Sinno and R. A. Brown, J. Electrochem. Soc. 146, 2300 (1999).
T. L. Larsen, L. Jensen, A. Ludge, H. Riemann, and H. Lemke, J. Cryst. Growth 230, 300 (2001).
W. Wijaranakula, J. Electrochem. Soc. 139, 604 (1992).
R. Habu and A. Tomura, Jpn. J. Appl. Phys. 35, 1 (1996).
P. B. Rasband, P. Clancy, and M. O. Thompson, J. Appl. Phys. 79, 12 (1996).
M. Akatsuka, M. Okui, S. Umeno, and K. Sueoka, J. Electrochem. Soc. 150, G587 (2003).
A. Voigt, C. Weichmann, J. Nitschkowski, E. Dornberger, and R. Holz, Cryst. Res. Technol. 38, 499 (2003).
H. Lemke and W. Sudkamp, Phys. Status Solidi A 176, 843 (1999).
V. V. Voronkov, J. Cryst. Growth 59, 625 (1982).
A. J. R. de Kock, P. J. Roksnoer, and P. G. T. Boonen, J. Cryst. Growth 30, 279 (1975).
P. J. Roksnoer and M. M. B. von den Boom, J. Cryst. Growth 53, 563 (1981).
J. Furukawa, H. Tanaka, Y. Nakada, N. Ono, and S. Shiraki, J. Cryst. Growth 210, 26 (2000).
M. Kato, T. Yoshida, Y. Ikeda, and Y. Kitagawara, Jpn. J. Appl. Phys. 35, 5597 (1996).
H. Foll and B. O. Kolbesen, J. Appl. Phys. 8, 319 (1975).
M. Itsumi, J. Cryst. Growth 237–239, 1773 (2002).
V. I. Talanin and I. E. Talanin, Phys. Status Solidi A 200, 297 (2003).
V. I. Talanin, I. E. Talanin, and D. I. Levinzon, Cryst. Res. Technol. 37, 983 (2002).
V. I. Talanin, I. E. Talanin, and D. I. Levinzon, Crystallogr. Rep. 49(2), 188 (2004).
V. I. Talanin and I. E. Talanin, Defects Diffus. Forum 230–232, 177 (2004).
S. M. Hu, J. Vac. Sci. Technol. 14, 17 (1977).
E. Sirtl, in Semiconductor Silicon, Ed. by H. R. Huff and E. Sirtl (Princeton, New York, 1977), p. 4.
U. Gösele, W. Frank, and A. Seeger, Appl. Phys. A 23, 361 (1980).
U. Gösele, W. Frank, and A. Seeger, Solid State Commun. 45, 31 (1983).
J. Dzelme, I. Ertsinsh, B. Zapol, and A. Misiuk, Phys. Status Solidi A 171, 197 (1999).
L. Fedina, A. Gutakovskii, A. Aseev, J. van Landujt, and J. Vanhellemont, Phys. Status Solidi A 171, 147 (1999).
L. Fedina, A. Gutakovskii, and A. Aseev, Cryst. Res. Technol. 35, 775 (2000).
M. Ian Hodge, J. Res. Natl. Inst. Stand. Technol. 102, 195 (1997).
M. Tang, L. Colombo, J. Zhu, and T. Diaz de la Rubia, Phys. Rev. B: Condens. Matter 55, 14279 (1997).
H. J. Mayer, H. Mehrer, and K. Maier, in Proceedings of the International Conference on Radiation Effects in Semiconductors, Dubrovnik, Croatia, 1976, Ed, by N. B. Urli and J. W. Corbett (IOP, Bristol, 1977), p. 186.
H. Bracht, E. E. Haller, and R. Clark-Phelps, Phys. Rew. Lett. 81, 393 (1998).
G. Adam and J. H. Gibbs, J. Chem. Phys. 43, 139 (1965).
D. A. Antoniadis and I. Moskowitz, J. Appl. Phys. 53, 9214 (1982).
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Original Russian Text © V.I. Talanin, I.E. Talanin, 2007, published in Fizika Tverdogo Tela, 2007, Vol. 49, No. 3, pp. 450–453.
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Talanin, V.I., Talanin, I.E. On the recombination of intrinsic point defects in dislocation-free silicon single crystals. Phys. Solid State 49, 467–471 (2007). https://doi.org/10.1134/S1063783407030134
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DOI: https://doi.org/10.1134/S1063783407030134