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Correlation dependences in infrared spectra of metal phthalocyanines

Abstract

Metal-phthalocyanine (MPc) complexes CoPc, CuPc, CuPcCl15–16, CuPc(4-NO2-5-OPh)4, CuPc(4-CH2-phthalimide)4, CuPc(4-NO2-5-NHPhBr)4, PdPc, MgPc, PbPc, EuOAcPc, SmOAcPc, SmPc2, and YOAcPc were obtained and studied using IR spectroscopy. The correlation between the shift of the absorption band maximum in the range of 1100–1600 cm−1 and the atomic radius of template metal is found. It is shown that the planarity of the macrocycle of peripherally substituted CuPc can be estimated from the characteristics of the IR spectra.

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Original Russian Text © A.V. Ziminov, S.M. Ramsh, E.I. Terukov, I.N. Trapeznikova, V.V. Shamanin, TA. Yurre, 2006, published in Fizika i Tekhnika Poluprovodnikov, 2006, Vol. 40, No. 10, pp. 1161–1166.

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Ziminov, A.V., Ramsh, S.M., Terukov, E.I. et al. Correlation dependences in infrared spectra of metal phthalocyanines. Semiconductors 40, 1131–1136 (2006). https://doi.org/10.1134/S1063782606100022

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  • DOI: https://doi.org/10.1134/S1063782606100022

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