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Pink splash of active nitrogen in the discharge afterglow

  • Low-Temperature Plasma
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Abstract

Results are presented from experimental studies of the glow dynamics of active nitrogen in the stage of its excitation by a current pulse and during the discharge afterglow. The mechanism is proposed for the generation of a light splash in a highly activated nitrogen after the end of its pulsed excitation. The key role in the generation of this splash is played by the D-V processes, by which the dissociation energy is transferred to the vibrational degrees of freedom in the course of recombination of nitrogen atoms, and the V-E processes, by which the vibrational energy of highly excited molecules N2(X, v ≥ 25–27) is transferred to the emitting electronic states N2(B, v) after the V-V delay. Results of simulations based on the mechanism proposed are also presented.

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References

  1. B. Brocklehurst and K. R. Jennings, Prog. React. Kin. 4, 1 (1967).

    Google Scholar 

  2. G. E. Beale and H. P. Broida, J. Chem. Phys. 31, 1030 (1959).

    Article  ADS  Google Scholar 

  3. O. Oldenberg, Bull. Am. Phys. Soc. 12, 217 (1967); Report AFCRL-67-0365 (Air Force Cambridge Res. Labs., Bedford, MA, 1967).

    Google Scholar 

  4. A. M. Bass, J. Chem. Phys. 40, 695 (1964).

    Article  ADS  Google Scholar 

  5. Y. Tanaka, F. R. Innes, A. S. Jursa, and M. Nakamura, J. Chem. Phys. 42, 1183 (1965).

    Article  ADS  Google Scholar 

  6. B. Brocklehurst and R. W. Nicholls, Nature 223, 824 (1969).

    Article  ADS  Google Scholar 

  7. P. Supiot, O. Dessaux, and P. Goudmand, J. Phys. D 28, 1826 (1995).

    Article  ADS  Google Scholar 

  8. P. Supiot, D. Blois, S. De Benedictis, et al., J. Phys. D 32, 1887 (1999).

    Article  ADS  Google Scholar 

  9. D. Blois, P. Supiot, M. Barj, et al., J. Phys. D 31, 2521 (1998).

    Article  ADS  Google Scholar 

  10. C. Foissac, P. Supiot, O. Dessaux, and P. Goudmand, Plasma Sources Sci. Technol. 8, 603 (1999).

    Article  ADS  Google Scholar 

  11. S. Mazouffre, C. Foissac, P. Supiot, et al., Plasma Sources Sci. Technol. 10, 168 (2001).

    Article  ADS  Google Scholar 

  12. C. Foissac, A. Campargue, A. Kachanov, et al., J. Phys. D 33, 2434 (2000).

    Article  ADS  Google Scholar 

  13. N. Sadeghi, C. Foissac, and P. Supiot J. Phys. D 34, 1779 (2001).

    Article  ADS  Google Scholar 

  14. S. De Benedictis and G. Dilecce, Pure Appl. Chem. 74, 317 (2002).

    Google Scholar 

  15. F. Krema and V. Mazankova, in Proceedings of XXVII International Conference on Phenomena in Ionized Gazes, Eindhoven, 2005, p. 01–223.

  16. J. Levaton, J. Amorim, A. R. Souza, et al., J. Phys. D 35, 689 (2002).

    Article  ADS  Google Scholar 

  17. J. Levaton, A. Ricard, J. Henriques, et al., J. Phys. D 39, 3285 (2006).

    Article  ADS  Google Scholar 

  18. K. A. Vereschagin, V. V. Smirnov, and V. A. Shakhatov, Zh. Tekh. Fiz. 67(5), 34 (1997) [Tech. Phys. 42, 487 (1997)].

    Google Scholar 

  19. J. Loureiro, C. M. Ferreira, M. Capitelli, et al., J. Phys. D 23, 1371 (1990).

    Article  ADS  Google Scholar 

  20. V. Guerra, P. A. Sá, and J. Loureiro, Eur. Phys. J. Appl. Phys. 28, 125 (2004).

    Article  ADS  Google Scholar 

  21. V. Guerra and J. Loureiro, Plasma Sources Sci. Technol. 6, 361 (1997).

    Article  ADS  Google Scholar 

  22. P. A. Sá and J. Loureiro, J. Phys. D 30, 2320 (1997).

    Article  ADS  Google Scholar 

  23. E. Tatarova, F. M. Dias, C. M. Ferreira, et al., J. Phys. D 30, 2663 (1997).

    Article  ADS  Google Scholar 

  24. P. A. Sá, V. Guerra, J. Loureiro, and N. Sadeghi, J. Phys. D 37, 221 (2004).

    Article  ADS  Google Scholar 

  25. J. Loureiro, P. A. Sá, and V. Guerra, J. Phys. D 39, 122 (2006).

    Article  ADS  Google Scholar 

  26. J. Loureiro, P. A. Sá, and V. Guerra, J. Phys. D 34, 1769 (2001).

    Article  ADS  Google Scholar 

  27. V. Guerra, P. A. Sá, and J. Loureiro, J. Phys. D 34, 1745 (2001).

    Article  ADS  Google Scholar 

  28. V. Guerra, E. Galiaskarov, and J. Loureiro, Chem. Phys. Lett. 371, 576 (2003).

    Article  ADS  Google Scholar 

  29. B. F. Gordiets, C. M. Ferreira, V. L. Guerra, et al., IEEE Trans. Plasma Sci. 23, 750 (1995).

    Article  ADS  Google Scholar 

  30. V. N. Ochkin, Spectroscopy of Low-Temperature Plasmas (Fizmatlit, Moscow, 2006) [in Russian].

    Google Scholar 

  31. A. Lofthus and P. H. Krupenie, J. Phys. Chem. Ref. Data 6, 113 (1977).

    Article  ADS  Google Scholar 

  32. Yu. S. Akishev, K. V. Baiadze, V. M. Vetsko, et al., Fiz. Plazmy 11, 999 (1985) [Sov. J. Plasma Phys. 11, 582 (1985)].

    Google Scholar 

  33. Yu. S. Akishev, A. V. Dem’yanov, I. V. Kochetov, et al., Teplofiz. Vys. Temp. 20, 818 (1982).

    Google Scholar 

  34. L. G. Piper, J. Chem. Phys. 88, 231 (1988).

    Article  ADS  Google Scholar 

  35. L. G. Piper, J. Chem. Phys. 88, 6911 (1988).

    Article  ADS  Google Scholar 

  36. M. Capitelli, C. M. Ferreira, B. F. Gordiets, and A. I. Osipov, Plasma Kinetics in Atmospheric Gases (Springer-Verlag, Berlin, 2000).

    Google Scholar 

  37. D. I. Slovetskiĭ, Mechanisms for Chemical Reactions in Nonequilibrium Plasmas (Nauka, Moscow, 1980) [in Russian].

    Google Scholar 

  38. I. A. Kossyi, A. Yu. Kostinsky, A. A. Matveyev, and V. P. Silakov, Plasma Sources Sci. Technol. 1, 207 (1992).

    Article  ADS  Google Scholar 

  39. K. S. Krasnov, Molecules and Chemical Bounds (Vysshaya Shkola, Moscow, 1984) [in Russian].

    Google Scholar 

  40. T. G. Slanger and G. Black, J. Chem. Phys. 64, 4442 (1976).

    Article  ADS  Google Scholar 

  41. J. Anketell, Can. J. Phys. 55, 1134 (1977).

    ADS  Google Scholar 

  42. AVOGADRO (1992–1995) Database on Rate Constants of Chemical and Plasmachemical Reactions, RRATE, AVOGADRO Centre, Institute of Mechanics, Moscow State University, Moscow.

    Google Scholar 

  43. R. Nagpal and P. K. Ghosh, J. Phys. B 24, 3295 (1991).

    Article  ADS  Google Scholar 

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Original Russian Text © Yu.S. Akishev, M.E. Grushin, V.B. Karal’nik, A.V. Petryakov, N.I. Trushkin, 2007, published in Fizika Plazmy, 2007, Vol. 33, No. 9, pp. 828–845.

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Akishev, Y.S., Grushin, M.E., Karal’nik, V.B. et al. Pink splash of active nitrogen in the discharge afterglow. Plasma Phys. Rep. 33, 757–773 (2007). https://doi.org/10.1134/S1063780X07090061

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  • DOI: https://doi.org/10.1134/S1063780X07090061

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