Journal of Experimental and Theoretical Physics

, Volume 115, Issue 5, pp 759–768 | Cite as

Vibrational excitation of a molecule by a resonance current

  • M. A. KozhushnerEmail author
  • I. I. Oleinik
Atoms, Molecules, Optics


Correct expressions are obtained for calculating a tunnel-resonance current through molecules. The participation of molecular vibrations in the resonance charge transfer through a molecule and vibrational excitation of the molecule are determined by the reorganization energy E r of the vibrational system depending on the displacement of the equilibrium position of vibrational modes in passing from the neutral molecule to the resonance state of a molecular ion. The mean excitation energy of the molecule during the propagation of an elementary charge changes from E r at the voltage across electrodes close to the threshold up to 2E r at voltages considerably exceeding the threshold voltage. An expression is obtained for the stationary vibrational temperature of the molecule, which is proportional to the resonance current.


High Occupied Molecular Orbital Lower Unoccupied Molecular Orbital Neutral Molecule Resonance Current Vibrational Excitation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  1. 1.Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia
  2. 2.University of South FloridaTampaUSA

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