Abstract
An analysis of intermittent fluorescence is presented for a single molecule driven by a continuous-wave laser field. The interruptions of fluorescence are caused by transition of the molecule to a triplet state. A method previously developed to calculate photon distribution for continuous-wave fluorescence is applied to analyze photon statistics of fluorescence blinking. The probability w N (T) of counting N photons over a time interval T is derived for intermittent fluorescence. The photons counted over relatively short intervals are found to have a sub-Poissonian (narrower than Poisson) distribution. The photon distribution over intervals longer than the mean off time has a complicated form with two maxima; i.e., a super-Poissonian (wider than Poisson) distribution is obtained.
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References
L. Mandel, Opt. Lett. 4, 205 (1979).
L. Mandel and E. Wolf, Optical Coherence and Quantum Optics (Cambridge Univ. Press, Cambridge, 1995; Fizmatlit, Moscow, 2000).
W. Nagourney, J. Sandberg, and H. Dehmelt, Phys. Rev. Lett. 56, 2797 (1986).
T. Sauter, W. Neuhauser, R. Blatt, and P. E. Toschek, Phys. Rev. Lett. 57, 1696 (1986).
J. Bergquist, R. G. Hulet, W. M. Itano, and D. J. Wineland, Phys. Rev. Lett. 57, 1699 (1986).
J. Javanainen, Phys. Rev. A 33, 2121 (1986).
A. Schenzle, D. G. DeVoe, and R. G. Brewer, Phys. Rev. A 33, 2127 (1986).
C. Cohen-Tannoudji and J. Dalibard, Europhys. Lett. 1, 441 (1986).
D. T. Pegg, R. Loudon, and P. L. Knight, Phys. Rev. A 33, 4085 (1986).
F. Diedrich and H. Walther, Phys. Rev. Lett. 58, 203 (1987).
M. S. Kim and P. L. Knight, Phys. Rev. A 36, 5265 (1987).
W. M. Itano, J. C. Bergquist, and D. J. Wineland, Phys. Rev. A 38, 559 (1988).
M. Schubert, I. Siemers, R. Blatt, et al., Phys. Rev. Lett. 68, 3016 (1992).
M. B. Plenio and P. L. Knight, Rev. Mod. Phys. 70, 101 (1998).
I. S. Osad’ko, Eh. Éksp. Teor. Fiz. 128, 77 (2005) [JETP 101, 64 (2005)].
R. Short and L. Mandel, Phys. Rev. Lett. 51, 384 (1983).
E. Barkai, Y. J. Jung, and R. Silbey, Phys. Rev. Lett. 87, 207403 (2001).
Y. Zheng and F. L. H. Brown, J. Chem. Phys. 121, 3238 (2004).
Y. He and E. Barkai, Phys. Rev. Lett. 93, 068302 (2004).
I. S. Osad’ko and D. N. Gus’kov, J. Lumin. (2007) (in press).
I. S. Osad’ko, Zh. Éksp. Teor. Fiz. 113, 1606 (1998) [JETP 86, 875 (1998)].
I. S. Osad’ko, Selective Spectroscopy of Single Molecules (Fizmatlit, Moscow, 2000; Springer, Berlin, 2002), Springer Ser. Chem. Phys., Vol. 69.
B. R. Mollow, Phys. Rev. A 12, 1919 (1975).
Y. Zheng and F. L. H. Brown, Phys. Rev. Lett. 90, 238305 (2003).
Y. Zheng and F. L. H. Brown, J. Chem. Phys. 119, 11814 (2003).
I. S. Osad’ko and L. B. Yershova, J. Lumin. 87–89, 184 (2000).
I. S. Osad’ko and L. B. Yershova, J. Chem. Phys. 112, 9645 (2000).
T. Ha, Th. Enderle, D. S. Chemla, et al., Chem. Phys. Lett. 271, 1 (1997).
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Original Russian Text © I.S. Osad’ko, 2007, published in Zhurnal Éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2007, Vol. 131, No. 6, pp. 978–993.
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Osad’ko, I.S. Sub- and super-Poissonian photon statistics of single-molecule fluorescence blinking. J. Exp. Theor. Phys. 104, 853–865 (2007). https://doi.org/10.1134/S1063776107060039
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DOI: https://doi.org/10.1134/S1063776107060039