Abstract
Yttrium‒aluminum garnet single crystals, including cerium-doped ones, have been grown from melt by Bagdasarov’s method. A comparative spectroscopy study of garnet single crystals and specially prepared ceramics of the same composition has been carried out. The comparative analysis suggests that an increase in the concentration of cerium ions in the garnet crystals improves the spectral-luminescence and scintillation characteristics of the latter and facilitates effective quenching of the substrate luminescence. Ways of optimizing the synthesis conditions to improve the efficiency of scintillators based on {Y\(_{{1-x}}\)Cex}3Al5O12 garnet crystal have been proposed.
REFERENCES
A. A. Kaminskii, Laser Photonics Rev. 1 (2), 93 (2007). https://doi.org/10.1002/lpor.200710008
https://www.crystals.saint-gobain.com/garnet-substrates
T. Yanagida, H. Takahashi, T. Ito, et al., IEEE Trans. Nucl. Sci. 52 (5), 1836 (2005). https://doi.org/10.1109/TNS.2005.856757
E. Mihóková, M. Nikl, J. A. Mareš, et al., J. Lumin. 126, 77 (2007). https://doi.org/10.1016/j.jlumin.2006.05.004
P. Lecoq, A. Gektin, and M. Korzhik, Inorganic Scintillators for Detector Systems (Springer, Cham, 2017), p. 1.
R. C. Linares, Solid State Commun. 2, 229 (1964). https://doi.org/10.1016/0038-1098(64)90369-2
A. Wagner, B. Ratzker, S. Kalabukhov, et al., Ceram. Int. 45, 12279 (2019). https://doi.org/10.1016/j.ceramint.2019.03.141
B. V. Mill’, Magnetic and Crystallochemical Studies of Ferrites (Izd-vo MGU, Moscow, 1971) [in Russian].
M. Allibert, C. Chatillon, J. Mareschal, and F. Lissalde, J. Cryst. Growth 23, 289 (1974). https://doi.org/10.1016/0022-0248(74)90071-2
M. Kh. Ashurov, Yu. Voronko, V. V. Osiko, et al., Phys. Status Solidi A 42 (1), 101 (1977). https://doi.org/10.1002/pssa.2210420108
A. A. Kaminskii, A. V. Butashin, K. S. Aleksandrov, and L. N. Bezmaternykh, Crystallogr. Rep. 47 (2), 308 (2002).
Kh. S. Bagdasarov, High-Temperature Crystallization from Melt (Fizmatlit, Moscow, 2004) [in Russian].
Ch. R. Varney and F. A. Selim, AIMS Mater. Sci. 2 (4), 560 (2015). https://doi.org/10.3934/matersci.2015.4.560
A. A. Kaminsky, L. K. Aminov, V. L. Ermolaev, et al., Physics and Spectroscopy of Laser Crystals (Moscow, Nauka, 1986).
A. H. Lumpkin, A. B. Garson, and M. A. Anastasio, Rev. Sci. Instrum. 89 (7), 073704 (2018). https://doi.org/10.1063/1.5027499
V. B. Kvartalov, V. M. Kanevskii, V. A. Fedorov, and A. V. Butashin, Advances in Chemistry and Chemical Technology: Collected Works, Vol. XXXVI, No. 7 (Izd-vo RKhTU im. D.I. Mendeleeva, Moscow, 2022).
P. A. Rodnyi, S. B. Mikhrin, A. N. Mishin, and A. V. Sidorenko, IEEE Trans. Nucl. Sci. 48 (6), 2340 (2001). https://doi.org/10.1109/23.983264
G. Zhao, X. Zeng, J. Xu, et al., J. Cryst. Growth 253, 290 (2003). https://doi.org/10.1016/S0022-0248(03)01017-0
A. G. Petrosyan, Kh. S. Bagdasarov, T. N. Butaeva, et al., Kristallografiya 20 (5), 1089 (1975).
S. V. Nizhankovsky, A. Ya. Dan’ko, V. M. Puzikov, et al., Funct. Mater. 15 (4), 546 (2008).
F. Bantien, P. Albers, and G. Huber, J. Lumin. 36, 363 (1987). https://doi.org/10.1016/0022-2313(87)90153-0
Ch. Lin, Bull. Minèral. 104, 218 (1981).
Yu. Zorenko, A. Voloshinovskii, V. Savchyn, et al., Phys. Status Solidi B 244 (6), 2180 (2007). https://doi.org/10.1002/pssb.200642431
Funding
This study was carried out within the State assignment of the Ministry of Science and Higher Education of the Russian Federation for the Federal Research Center “Crystallography and Photonics” of the Russian Academy of Sciences in the part concerning the growth of garnet crystals and preparation of the samples for investigations and crystal chemical analysis, and within the Agreement with the Ministry of Science and Higher Education of the Russian Federation of October 12, 2021, no. 075-15-2021-1362 in the part concerning the spectroscopy study and characterization of the obtained materials as elements of scintillation detectors of ionizing radiation.
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Butashin, A.V., Venevtsev, I.D., Fedorov, V.A. et al. Optical and X-ray Spectroscopy of Color Centers in Cerium-Doped Yttrium‒Aluminum Garnet. Crystallogr. Rep. 68, 594–599 (2023). https://doi.org/10.1134/S1063774523700268
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DOI: https://doi.org/10.1134/S1063774523700268