Skip to main content
SpringerLink
Log in

Synthesis and Structural Characterization of a Di-nuclear Uranyl Complex with Quinoline-6-carboxylate

  • STRUCTURE OF ORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

A di-nuclear uranyl complex with the formula of [(UO2)2(L)4(H2O)2]⋅4H2O (1) (HL = quinoline-6-carboxylic acid) was synthesized hydrothermally and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. Each U(VI) atom has typical pentagonal bipyramid geometry with two O atoms from uranyl, one O atom from one water molecule, and four O atoms from three L ligands. Complex 1 is linked by versatile hydrogen bonds to generate a 3D supramolecular uranyl organic framework.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. T. Loiseau, I. Mihalcea, N. Henry, et al., Coord. Chem. Rev. 266–267, 69 (2014).

    Article  Google Scholar 

  2. J. Harrowfield and P. Thuéry, Chemistry 2, 63 (2020).

    Article  Google Scholar 

  3. Z.-T. Yu, Z.-L. Liao, Y.-S. Jiang, et al., Chem. Commun. 50, 1814 (2004).

    Article  Google Scholar 

  4. Y. Li, S. A. Rizvi, D. Hu, et al., Angew. Chem., Int. Ed. 131, 13633 (2019).

    Article  ADS  Google Scholar 

  5. P. Li, N. A. Vermeulen, X. G, et al., Angew. Chem., Int. Ed. 55, 10514 (2016).

  6. K.-Q. Hu, Z.-W. Huang, Z.-H. Zhang, et al., Chem. Eur. J. 24, 16766 (2018).

    Article  Google Scholar 

  7. F. Hu, Z. Di, P. Lin, et al., Cryst. Growth Des. 18, 576 (2018).

    Article  Google Scholar 

  8. L. Shao, F. Zhai, Y. Wang, et al., Dalton Trans. 48, 1595 (2019).

    Article  Google Scholar 

  9. Z. Bai, Y. Wang, Y. Li, et al., Inorg. Chem. 55, 6358 (2016).

    Article  Google Scholar 

  10. W. Xu, Y.-N. Ren, M. Xie, et al., Dalton Trans. 47, 4236 (2018).

    Article  Google Scholar 

  11. N. Zhang, Y.-H. Xing, and F.-Y. Bai, Inorg. Chem. 58, 6866 (2019).

    Article  Google Scholar 

  12. L. Wang, W. Xu, W.-Y. Li, et al., Chem. Asian J. 14, 4246 (2019).

    Article  Google Scholar 

  13. K. P. Carter, T. D. Lohrey, D. Reilly, et al., Chem. Eur. J. 26, 13819 (2020).

    Article  Google Scholar 

  14. J. Song, X. Gao, Z. N. Wang, et al., Inorg. Chem. 54, 9046 (2015).

    Article  Google Scholar 

  15. J. Xie, Y. Wang, W. Liu, et al., Angew. Chem., Int. Ed. 56, 7500 (2017).

    Article  Google Scholar 

  16. S. Chorazy, J. J. Zakrzewski, M. Reczynski, et al., Chem. Commun. 55, 3057 (2019).

    Article  Google Scholar 

  17. Y. Cai, W. Zhang, Q. Sun, et al., J. Coord. Chem. 61, 3350 (2008).

    Article  Google Scholar 

  18. N. P. Deifel and C. L. Cahill, Chem. Commun. 47, 6114 (2011).

    Article  Google Scholar 

  19. X. Gao, C. Wang, Z.-F. Shi, et al., Dalton Trans. 44, 11562 (2015).

    Article  Google Scholar 

  20. K. P. Carter, M. Kalaj, A. Kerridge, et al., CrystEngComm 20, 4916 (2018).

    Article  Google Scholar 

  21. K. Darzinezhad, M. M. Amini, E. Mohajerani, et al., Dalton Trans. 48, 3695 (2019).

    Article  Google Scholar 

  22. V. E. Mistryukov, Y. N. Mikhailov, I. A. Yuranov, et al., Koord. Khim. 9, 272 (1983).

    Google Scholar 

  23. A. Navaza, M. G. Iroulart, M. Nierlich, et al., Acta Crystallogr. C 49, 1767 (1993).

    Article  Google Scholar 

  24. P. D. Bernardo, P. L. Zanonato, F. Benetollo, et al., Inorg. Chem. 51, 9045 (2012).

    Article  Google Scholar 

  25. L. Mei, C.-Z. Wang, L. Wang, et al., Cryst. Growth Des. 15, 1395 (2015).

    Article  Google Scholar 

  26. Bruker, APEX2, SAINT, SADABS (Bruker AXS Inc., Madison, WI, 2008).

  27. G. M. Sheldrick. Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

  28. G. M. Sheldrick. Acta Crystallogr. C 71, 3 (2015).

    Article  Google Scholar 

  29. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009).

    Article  Google Scholar 

  30. X.-M. Wang, C. Wang, N. Zhang, et al., Chem. Sel. 5, 8625 (2020).

    Google Scholar 

Download references

ACKNOWLEDGMENTS

We are grateful for the financial support from the National Key Research and Development Program of China (no. 2020YFC1909001) and the Key Scientific and Technological Research Projects in Henan Province (no. 192102210028).

Author information

Authors and Affiliations

  1. Faculty of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, 341000, Ganzhou, P.R. China

    Y. Meng, Q. Lan, F. Niu, X. Zhang & Y. Yang

  2. School of Chemistry and Chemical Engineering, Zhoukou Normal University, 466001, Zhoukou, P.R. China

    B. Cai

  3. National Engineering Research Center for Ionic Rare Earth, 341000, Ganzhou, China

    Y. Yang

Authors
  1. Y. Meng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Cai
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Q. Lan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. X. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Y. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Y. Yang.

Ethics declarations

The authors declare no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Supplementary Information

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Meng, Y., Cai, B., Lan, Q. et al. Synthesis and Structural Characterization of a Di-nuclear Uranyl Complex with Quinoline-6-carboxylate. Crystallogr. Rep. 67, 224–228 (2022). https://doi.org/10.1134/S1063774522020092

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774522020092

Search

Navigation