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Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Constructed by Bis(4-(1H-Imidazol-1-yl)phenyl) Methanone and 1,4-Benzenedicarboxylate Ligands

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Abstract

A coordination polymer with the V-shaped ligands, {Cd2(bipmo)2(bdc)2⋅H2O}n (1), (where bipmo is bis(4-(1H-imidazol-1-yl)phenyl)methanone; H2bdc is 1,4-benzenedicarboxylic acid) has been prepared and structural characterized by IR, elemental analyses and single-crystal X-ray diffraction. X-ray diffraction analyses show that the Cd(II) ion is in a distorted octahedral environment, of which the donor atoms are provided by oxygen atoms of the bdc2– ligands and nitrogen atoms of the bipmo ligands. From a topological point of view, the framework of 1 exhibits two-fold 3D uninodal six-connected interpenetrating framework with the (412 ⋅ 63) pcu topology.

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ACKNOWLEDGMENTS

We are grateful for financial support from the Young Teacher Starting-up Research of Yuncheng University (YQ-2019022), the Priority Academic Program of Applied Chemistry (XK-2019057), Applied Research Projects of Yuncheng University (CY-2018019) and Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (2019L0857).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000 P. R., Yuncheng, China

    G.-F. Wang, S.-W. Sun, H. Sun, S.-F. Song & H.-S. Jiang

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  1. G.-F. Wang
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  2. S.-W. Sun
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  3. H. Sun
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  4. S.-F. Song
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  5. H.-S. Jiang
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Correspondence to G.-F. Wang.

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Wang, GF., Sun, SW., Sun, H. et al. Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Constructed by Bis(4-(1H-Imidazol-1-yl)phenyl) Methanone and 1,4-Benzenedicarboxylate Ligands. Crystallogr. Rep. 66, 1253–1257 (2021). https://doi.org/10.1134/S1063774521070208

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