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Nanocomposites Based on Poly(Amide-Imide) Matrix with Na–Mg Triple Chain Hydrosilicate

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Abstract

A new polymer-inorganic nanocomposite composed of fibrous Na–Mg triple chain hydrosilicate with a poly(amide-imide) matrix was developed. Its structure, morphology, and dynamic mechanical properties were studied. Stability and high values of mechanical characteristics were shown in a wide temperature range from –150 to 300°C for both the polymer and a composite based on it. The introduction of the fibrous hydrosilicate nanofiller led to a structuring of the polymer matrix and a change from an amorphous state to an ordered mesomorphic state. A comparative analysis of the free and cryo-fracture surface morphologies of the polymer films and composites was carried out. A model of the structure of the polymer matrix with a network of hydrogen bonds, the density of which depends on the reduced viscosity of the casting solution, was proposed.

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ACKNOWLEDGMENTS

This work was supported by the Ministry of Science and Higher Education of the Russian Federation and was performed owing to cooperation between the Institute of Macromolecular Compounds of the Russian Academy of Sciences and the “Petru Poni” Institute of Macromolecular Chemistry of the Romanian Academy of Sciences (program of collaboration “Multifunctional polymers and nanocomposites”).

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Science, St. Petersburg, Russia

    G. N. Gubanova, S. V. Kononova, D. A. Sapegin, N. N. Saprykina & A. Ya. Volkov

  2. “Petru Poni” Institute of Macromolecular Chemistry, Romanian Academy, Iaşi, Romania

    D. Timpu & M. Cristea

  3. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Science, St. Petersburg, Russia

    E. N. Korytkova

  4. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences, Moscow, Russia

    V. V. Klechkovskaya

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  1. G. N. Gubanova
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  2. D. Timpu
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  3. M. Cristea
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  4. S. V. Kononova
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  5. E. N. Korytkova
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  8. A. Ya. Volkov
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  9. V. V. Klechkovskaya
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Correspondence to G. N. Gubanova.

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Gubanova, G.N., Timpu, D., Cristea, M. et al. Nanocomposites Based on Poly(Amide-Imide) Matrix with Na–Mg Triple Chain Hydrosilicate. Crystallogr. Rep. 66, 1185–1199 (2021). https://doi.org/10.1134/S1063774521070063

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