Skip to main content
SpringerLink
Log in

Structure of Organic Compound (E)-3-((S)1-Phenylethylamine)methylene R (+) Camphor

  • STRUCTURE OF ORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The synthesis and crystal structure of (E)-3-((S)-1-phenylethylamine)methylene R-(+) camphor are discussed. The 1H NMR spectrum in a chloroform solution indicates the existence of a mixture of two tautomers, the main tautomer corresponds to the E-isomer. On the other hand, in the solid state, the crystal structure solved by X-ray diffraction shows only the occurrence of this latter form. Crystal data: monoclinic (P21), a = 11.019(4) Å, b = 6.782(2) Å, c = 11.186(4) Å, β = 101.843(4)°.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. W. Oppolser, Pure Appl. Chem. 62 (7), 1241 (1990).

    Article  Google Scholar 

  2. O. B. Olubanwo, J. A. Golen, A. L. Rheingold, and V. Nevalainen, Int. J. Org. Chem. 8, 240 (2018).

    Article  Google Scholar 

  3. V. D. Singha, V. V. Salianb, B. Narayanab, et al., Crystallogr. Rep. 62 (7), 1157 (2017).

    Article  ADS  Google Scholar 

  4. R. F. W. Bader, Atoms in Molecules: A Quantum Theory (Oxford Univ. Press, 1990).

    Google Scholar 

  5. R. F. W. Bader, Chem. Rev. 91, 893 (1991).

    Article  Google Scholar 

  6. R. L. Lintvedt and A. M. Fatta, Inorg. Chem. 7, 2489 (1968).

    Article  Google Scholar 

  7. A. I. Koltsov, J. Mol. Struct. 444, 1 (1998).

    Article  ADS  Google Scholar 

  8. C. R. Groom, I. J. Bruno, M. P. Lightfoot, and S. C. Ward, Acta Crystallogr. B 72, 171 (2016).

    Article  Google Scholar 

  9. Bruker, SMART, V5.624. Data Collection Software (Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 2001).

  10. Bruker, SAINT, V6.22A (Including SADABS). Data Reduction Software (Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 2002).

  11. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

  12. G. M. Sheldrick, Acta Crystallogr. C 71, 3 (2015).

    Article  Google Scholar 

  13. M. J. Frisch, G. W. Trucks, H. B. Schlegel, et al., GAUSSIAN 09, Revision A.1 (Gaussian Inc., Wallingford, CT, USA, 2009).

    Google Scholar 

  14. A. Foi, R. S. Correa, J. Ellena, et al., J. Mol. Struct. 1059, 1 (2014).

    Article  ADS  Google Scholar 

  15. M. Di Paolo, M. L. Bossi, R. Baggio, and S. A. Suarez, Acta Crystallogr. B 72, 684 (2016).

    Article  Google Scholar 

  16. G. Wang, Z. Chen, Z. Xu, et al., J. Phys. Chem. B 120 (4), 610 (2016).

    Article  Google Scholar 

  17. T. Lu and F. Chen, J. Comput. Chem. 33, 580 (2012).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química, Facultad de Ciencias Naturales, Universidad Metropolitana de Ciencias de la Educación, Ciencias, Chile

    A. Miranda

  2. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Concepción, Edmundo Larenas 234, Concepción, Chile

    P. Arroyo & M. Zarraga

  3. INQUIMAE, CONICET and Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Núñez (C1428EHA), CABA, Argentina

    S. A. Suarez

  4. Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina

    R. Baggio

  5. Facultad de Ciencias Básicas, Universidad Santo Tomás, Limonares 190, Viña del Mar, Chile

    Y. Moreno

Authors
  1. A. Miranda
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Arroyo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Zarraga
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Suarez
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. Baggio
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Y. Moreno
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to A. Miranda, M. Zarraga or Y. Moreno.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Miranda, A., Arroyo, P., Zarraga, M. et al. Structure of Organic Compound (E)-3-((S)1-Phenylethylamine)methylene R (+) Camphor. Crystallogr. Rep. 65, 1150–1155 (2020). https://doi.org/10.1134/S1063774520070111

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774520070111

Search

Navigation