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Hydrothermal Synthesis, Characterization, and Property of a Thulium Dinuclear Complex Based on Sulfonate-Phenol Ligand and 1,10-Phenanthroline

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Abstract

A new lanthanide metal complex [Tm2(H2L)3(phen)2] (1) (Na2H2L = 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium salt, phen = 1,10-phenanthroline) was synthesized by hydrothermal method. It has been characterized by single crystal X-ray diffraction, elemental analysis and thermogravimetric (TG) analysis. The X-ray diffraction analysis revealed that the dinuclear thulium complex is formed with three bridged H2L2– ligands and one phen molecule around each thulium center. The center thulium atoms are eight-coordinate in distorted double-capped triangular prism and dodecahedral geometries, respectively. Each bridged H2L2– acts as a tetradentate ligand with a non-coordinated sulfonate group. To the best of our knowledge, complex 1 is the first example of a dinuclear H2L2–-bridged lanthanide complex with phen molecules. It exhibits the fluorescent emission at 475, 538, and 615 nm, which are attributed to the 1G4-3H6, 1D2-3H4, and 1G4-3H4 transitions of thulium ion, respectively.

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Funding

Scientific Research Fund Project of Liaoning Provincial Education Department (No. L2019010).

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Authors and Affiliations

  1. School of Chemistry and Materials Science, Liaoning Shihua University, 113001, Fushun, China

    Lei Guan, Xin Wang & Ying Wang

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  1. Lei Guan
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  2. Xin Wang
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  3. Ying Wang
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Correspondence to Lei Guan.

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Lei Guan, Wang, X. & Wang, Y. Hydrothermal Synthesis, Characterization, and Property of a Thulium Dinuclear Complex Based on Sulfonate-Phenol Ligand and 1,10-Phenanthroline. Crystallogr. Rep. 65, 1124–1128 (2020). https://doi.org/10.1134/S106377452007007X

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