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Synthesis and Crystal Structure of a Cobalt Coordination Polymer Based on Bis(4-(1H-imidazol-1-YL)phenyl)methanone and trans-1,2-Cyclohexanedicarboxylate

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An Erratum to this article was published on 20 November 2020

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Abstract

A cobalt coordination polymer with V-shaped ligands, {[L1Co(trans-CHDCA)] · 2H2O}n (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, trans-H2CHDCA = trans-1,2-cyclohexanedicarboxylic acid) has been synthesized under solvothermal conditions. It has been characterized by IR spectra, elemental analyses and single-crystal X-ray diffraction. The crystal is monoclinic, sp. gr. P21/c, Z = 4. In crystal, trans-CHDCA2– ions bridge Co atoms into wave-like chain along the c-axis. Furthermore, chains are linked by bis(4-(1H-imidazol-1-yl)phenyl)methanone to form 2D layers.

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  • 20 November 2020

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ACKNOWLEDGMENTS

This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2015007) and Applied Research Projects of Yuncheng University (no. CY-2018019).

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, China

    G.-F. Wang, S.-W. Sun, Y.-P. Tang & Y.-D. Zhu

  2. Science Laboratory Centre, Yuncheng University, 044000, Yuncheng, China

    Y.-F. Zhao, B.-H. Wei & L.-X. Meng

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  1. G.-F. Wang
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  2. S.-W. Sun
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  3. Y.-P. Tang
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  4. Y.-F. Zhao
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  5. B.-H. Wei
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  6. L.-X. Meng
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  7. Y.-D. Zhu
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Correspondence to G.-F. Wang.

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Wang, GF., Sun, SW., Tang, YP. et al. Synthesis and Crystal Structure of a Cobalt Coordination Polymer Based on Bis(4-(1H-imidazol-1-YL)phenyl)methanone and trans-1,2-Cyclohexanedicarboxylate. Crystallogr. Rep. 65, 453–456 (2020). https://doi.org/10.1134/S1063774520030347

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  • DOI: https://doi.org/10.1134/S1063774520030347

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