Abstract
A zinc coordination polymer with V-shaped ligands, [L1Zn(npa)]n (L1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H2npa = 4-nitrophthalic acid) has been synthesized under solvothermal conditions. The structure has been determined by single-crystal X-ray diffraction analysis and characterized by IR spectra, and elemental analyses. In crystal adjacent [Zn2(npa)2] units linked by four bridging ligands L1 form 2D layers, which are entangled between each other giving inclined interpenetration with the angle of 52.9°, thus resulting in a complicated 3D unique network. Moreover, luminescent properties of the title compound have been investigated.
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ACKNOWLEDGMENTS
This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2015007) and Applied Research Projects of Yuncheng University (no. CY-2018019).
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Gao-Feng Wang, Shu-Wen Sun Synthesis, Structure, and Luminescence of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and 4-Nitrophthalate Ligands. Crystallogr. Rep. 64, 1075–1079 (2019). https://doi.org/10.1134/S1063774519070265
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DOI: https://doi.org/10.1134/S1063774519070265