Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of Rubidium trans-Bis(N-methyliminodiacetato)chromate(III)

  • STRUCTURE OF INORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

A new rubidium salt, Rb[Cr(C5H7NO4)2] (C5H7NO4 = mida, methyliminodiacetate), was prepared and its molecular structure was determined from synchrotron X-ray data at 173 K. The complex crystallizes in the space group C2/c of the monoclinic system with four mononuclear formula units in a cell with dimensions a = 16.905(3) Å, b = 6.483(2) Å, c = 13.906(3) Å, and β = 113.95(3)°. The Cr atom is located in a center of symmetry with one independent Cr–N bond length of 2.081(2) Å and two Cr–O bond lengths of 1.9534(18) and 1.9628(18) Å. The Cr(III) ion is coordinated by two N atoms and four O atoms of symmetrical-facial mida ligands, displaying a distorted octahedral geometry. Hirshfeld surface analysis with 2D fingerprint plots revealed that the O···H, H···H, and O···Rb interactions are the main intermolecular interactions. The crystal structure is stabilized by the O···H, H···H, and O···Rb interactions among rubidium cation, the H atoms and the O atoms of carboxylate group from neighboring mida groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Scheme 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

REFERENCES

  1. L. Ronconi and P. J. Sadler, Coord. Chem. Rev. 251, 1633 (2007).

    Article  Google Scholar 

  2. A. Ross, J.-H. Choi, T. M. Hunter, et al., Dalton Trans. 41, 6408 (2012).

    Article  Google Scholar 

  3. J.-H. Choi and S. H. Lee, J. Mol. Struct. 932,84 (2009).

    Article  ADS  Google Scholar 

  4. J.-H. Choi, Inorg. Chim. Acta 362, 4231 (2009).

    Article  Google Scholar 

  5. J.-H. Choi, Chem. Phys. 256, 29 (2000).

    Article  Google Scholar 

  6. J.-H. Choi, Spectrochim. Acta A 56,1653 (2000).

    Article  ADS  Google Scholar 

  7. C. K. Poon and K. C. Pun, Inorg. Chem. 19, 568 (1980).

    Article  Google Scholar 

  8. D. M. Stearns and W. H. Armstrong, Inorg. Chem. 31, 5178 (1992).

    Article  Google Scholar 

  9. M. Nakano and S. Kawaguchi, Bull. Chem. Soc. Jpn. 52, 3563 (1979).

    Article  Google Scholar 

  10. R. Wernicke, H.-H. Schmidtke, and P. E. Hoggard, Inorg. Chim. Acta 24, 145 (1977).

    Article  Google Scholar 

  11. L. De Angelis, E. Aguglia, I. Allegranti, et al., Drugs Today 24, 733 (1988).

    Google Scholar 

  12. W. Fürst, P. Gouzerh, and Y. Jeannin, J. Coord. Chem. 8, 237 (1979).

    Article  Google Scholar 

  13. D. Mootz and H. Wunderlich, Acta Crystallogr. B 36, 445 (1980).

    Article  Google Scholar 

  14. H. Li, D.-J. Xu, and K.-L. Yin, Acta Crystallogr. E 59, m671 (2003).

    Article  Google Scholar 

  15. J.-S. Suh, S.-J. Park, K.-W. Lee, et al., Acta Crystallogr. C 53, 432 (1997).

    Article  Google Scholar 

  16. D. Moon and J.-H. Choi, Acta Crystallogr. E 72, 1190 (2016).

    Article  Google Scholar 

  17. D. Moon, K. S. Ryoo, and J.-H. Choi, Asian. J. Chem. 30, 588 (2018).

    Google Scholar 

  18. D. Mootz and H. Wunderlich, Acta Crystallogr. B 36, 721 (1980).

    Article  Google Scholar 

  19. D. Mootz and H. Wunderlich, Acta Crystallogr. B 36, 1189 (1980).

    Article  Google Scholar 

  20. D. Moon and J. H. Choi, Acta Crystallogr. E 71, 210 (2015).

    Article  Google Scholar 

  21. R. Meier, M. Molinier, C. Anson, et al., Dalton Trans. 5506 (2006).

  22. C. R. Groom, I. J. Bruno, M. P. Lightfoot, et al., Acta Crystallogr. B 72, 171 (2016).

    Article  Google Scholar 

  23. L. Fabbrizzi and A. Poggi, Chem. Soc. Rev. 42, 1681 (2013).

    Article  Google Scholar 

  24. M. Boiocchi, A. Broglia, L. Fabbrizzi, et al., Can. J. Chem. 92, 794 (2014).

    Article  Google Scholar 

  25. I.-H. Suh, J.-H. Lee, J.-H. Song, et al., J. Korean Phys. Soc. 29, 739 (1996).

    Google Scholar 

  26. J. W. Shin, K. Eom, and D. Moon, J. Synchrotron Rad. 23, 369 (2016).

    Article  Google Scholar 

  27. Z. Otwinowski and W. Minor, in Macromolecular Crystallography, Part A, 276, Ed. by C. W. Carter and R. M. Sweet, Jr. (Academic, New York, 1997), p. 307.

  28. G. M. Sheldrick, Acta Crystallogr. A 71, 3 (2015). b. G. M. Sheldrick, Acta Crystallogr. C 71, 3 (2015).

    Article  Google Scholar 

  29. K. Brandenburg and H. Putz, DIAMOND-3 (Univ. of Bonn, Germany, 2014).

  30. M. Zabel, V. I. Pavlovskii, and A. L. Poznyak, J. Struct. Chem. 50, 582 (2009).

    Article  Google Scholar 

  31. L. M. Shkol’nikova, N. V. Donchenko, A. L. Poznyak, et al., Zh. Strukt. Khim. 27, 89 (1986).

    Google Scholar 

  32. C. F. Matta, H. Hernand-Trujillo, T.-H. Tang, et al., Chem. Eur. J. 9, 1940 (2003).

    Article  Google Scholar 

  33. M. A. Spackman and D. Jayatilaka, CrystEngComm 11, 19 (2009).

    Article  Google Scholar 

  34. M. J. Turner, J. J. McKinnon, S. K. Wolff, et al., CrystalExplorer17 (Univ. of Western Australia, 2017).

    Google Scholar 

  35. M. A. Spackman and J. J. McKinnon, CrystEngComm 4, 378 (2002).

    Article  Google Scholar 

  36. J. J. McKinnon, M. A. Spackman, A. S. Mitchell, et al., Acta Crystallogr. B 60, 627 (2004).

    Article  Google Scholar 

  37. D. Moon, S. Tanaka, T. Akitsu, et al., J. Mol. Struct. 1154, 338 (2018).

    Article  ADS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was supported by a Research Grant of Andong National University. The X-ray crystallography experiment at PLS-II BL2D-SMC beamline was supported in part by MSIT and POSTECH.

Author information

Authors and Affiliations

  1. Pohang Accelerator Laboratory, POSTECH, 37673, Pohang, Korea

    D. Moon

  2. Department of Chemistry, Andong National University, 36729, Andong, Korea

    J.-H. Choi

Authors
  1. D. Moon
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J.-H. Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J.-H. Choi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Moon, D., Choi, JH. Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of Rubidium trans-Bis(N-methyliminodiacetato)chromate(III). Crystallogr. Rep. 64, 1011–1018 (2019). https://doi.org/10.1134/S1063774519070113

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774519070113

Search

Navigation