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Three Cu(II) Complexes Constructed by Flexible bis-Imidazole and Different Anions: From 0D Architecture to 2D Layer

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Abstract

Three new Cu(II) complexes, Cu(1,3-bip)(Ac)2 (I), {[Cu(H2O)2(1,3-bip)2] · (NO3)2}n (II), {[Cu(1,3-bip)(1,4-bdc)]2 · H2O · MeOH}n (III), where 1,3-bip is 1,3-bis(imidazole)propane and 1,4-bdc is terephthalic acid, have been synthesized and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that the complex I shows a zero-dimensional architecture, the complex II shows a one-dimensional loop-like chain, and the complex III shows a two-dimensional (4,4) grid layer structure. In addition, the thermal stability of complexes was investigated.

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REFERENCES

  1. J. F. Lu, S. T. Min, and H. G. Ge, J. Chem. Res. 38, 726 (2014).

    Article  Google Scholar 

  2. J. F. Lu, H. G. Ge, and J. Shi, J. Chem. Res. 39, 138 (2015).

    Article  Google Scholar 

  3. M. Eddaoudi, D. B. Moler, and H. Li, Acc. Chem. Res. 34, 319 (2001).

    Article  Google Scholar 

  4. J. S. Seo, D. Whang, and H. Lee, Nature 404, 982 (2000).

    Article  ADS  Google Scholar 

  5. G. J. Halder, C. J. Kepert, and B. K. Moubaraki, Science 298, 1762 (2002).

    Article  ADS  Google Scholar 

  6. P. X. Li and J. F. Lu, Chin. J. Struct. Chem. 32, 303 (2017).

    ADS  Google Scholar 

  7. J. F. Lu, L. X. Jin, H. G. Ge, et al., Chin. J. Struct. Chem. 36, 1810 (2017).

    Google Scholar 

  8. J. F. Lu, L. X. Jin, J. Song, et al., Chin. J. Struct. Chem. 37, 1814 (2018).

    Article  Google Scholar 

  9. J. F. Lu, X. L. Zhou, Y. H. Xu, et al., J. Chem. Res. 41, 526 (2018).

    Article  Google Scholar 

  10. S. Takamizawa, H. Yokoyama, and K. Mochizuki, Angew. Chem. Int. Ed. 42, 4331 (2003).

    Article  Google Scholar 

  11. D. N. Dybtsev, H. Chun, S. H. Yoon, and D. Kim, J. Am. Chem. Soc. 126, 32 (2004).

    Article  Google Scholar 

  12. B. Kesanli, Y. Cui, and M. R. Smith, Angew. Chem. Int. Ed. 44, 72 (2005).

    Article  Google Scholar 

  13. X. M. Gao, D. S. Li, J. J. Wang, and F. Fu, CrystEngComm 10, 479 (2008).

    Article  Google Scholar 

  14. M. L. Zhang, D. S. Li, J. J. Wang, and F. Fu, Dalton Trans. 47, 5355 (2009).

    Article  Google Scholar 

  15. L. L.Wen, Y. Z. Li, Z. D. Lu, and J. G. Lin, Cryst. Growth Des. 6, 530 (2006).

    Article  Google Scholar 

  16. J. Fan, C. Slebodnick, R. Angel, and B. E. Hanson, Inorg. Chem. 44, 552 (2005).

    Article  Google Scholar 

  17. G. H. Cui, J. R. Li, J. L. Tian, and X. H. Bu, Cryst. Growth Des. 5, 1775 (2005).

    Article  Google Scholar 

  18. H. A. Habib, J. Sanciz, and C. Janiak, Inorg. Chim. Acta 362, 2452 (2009).

    Article  Google Scholar 

  19. B. Wisser, Y. Lu, and C. Janiak, Z. Anorg. Allg. Chem. 633, 1189 (2007).

    Article  Google Scholar 

  20. SMART & SAINT, Software Reference Manuals, Version 6.22 (Bruker AXS, Madison, 2000).

  21. G M. Sheldrick, SADABS: Software for Empirical Absorption Correction (Univ. of Göttingen, Göttingen, 1996).

    Google Scholar 

  22. G. M. Sheldrick, Acta Crystallogr. C 71, 3 (2015).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

This work is supported by catalytic conversion team of syngas of Shaanxi University of Technology, National Natural Science Foundation of China (project no. 21373132), National Natural Science Foundation of Youth (project no. 21603133), Key Scientific Research Project of Education Department of Shaanxi Province (18JS023), and the Doctor Research Start Foundation of Shaanxi University of Technology (SLGQD2017-14).

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Authors and Affiliations

  1. Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, 723001, Hanzhong, China

    J. F. Lu, X. H. Yu, C. B. Zhao, N. Zheng, S. Y. Yue, L. Li, Z. H. Tang, H. G. Ge & L. X. Jin

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  1. J. F. Lu
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  2. X. H. Yu
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  3. C. B. Zhao
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  8. H. G. Ge
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Correspondence to H. G. Ge or L. X. Jin.

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Lu, J.F., Yu, X.H., Zhao, C.B. et al. Three Cu(II) Complexes Constructed by Flexible bis-Imidazole and Different Anions: From 0D Architecture to 2D Layer. Crystallogr. Rep. 64, 1055–1061 (2019). https://doi.org/10.1134/S1063774519070095

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  • DOI: https://doi.org/10.1134/S1063774519070095

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