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Synthesis, Structure, and Luminescent Properties of a Cadmium(II) Supramolecular Coordination Complex

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Abstract

A new supramolecular complex [Cd(dcbpy)(im)2(H2O)2] · 3H2O (H2dcbpy = 4,4'-dicarboxy-2,2'-bipyridine, im = imidazole) has been prepared under hydrothermal conditions. Its crystal structure is determined with single crystal X-ray diffraction. Cd2+ atom is six-coordinated by one dcbpy ligand, two imidazole and two water molecules. Each [Cd(dcbpy)(im)2(H2O)2] unit is connected to neighboring units through intermolecular O–H···O hydrogen bonds to form a three-dimensional supramolecular network structure. A topology method has been used to simplify the network. The stability and luminescent properties of the complex obtained have been investigated.

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ACKNOWLEDGMENTS

We gratefully acknowledge the financial support by Foundation of Hubei Educational Committee (grant no. D20172904).

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Authors and Affiliations

  1. Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, 438000, Huanggang, China

    Y. M. Chen, F. Peng, Q. C. Zhang, L. C. Huang & W. J. Zhang

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  1. Y. M. Chen
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  2. F. Peng
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  3. Q. C. Zhang
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  4. L. C. Huang
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  5. W. J. Zhang
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Correspondence to W. J. Zhang.

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Chen, Y.M., Peng, F., Zhang, Q.C. et al. Synthesis, Structure, and Luminescent Properties of a Cadmium(II) Supramolecular Coordination Complex. Crystallogr. Rep. 64, 1094–1098 (2019). https://doi.org/10.1134/S1063774519070046

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  • DOI: https://doi.org/10.1134/S1063774519070046

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