Abstract
The molecular structure of the title compound, C14H11ClN2O4, was determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic sp. gr. P21/c with Z = 4. The title compound, C14H11ClN2O4, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state.The molecule is almost planar and the dihedral angle between the planes of two aromatic ring is 2.2(1)°. The molecular structure is stabilized by intramolecular O–H···N hydrogen bond which generates a six-membered ring. In the crystal structure, the molecules are linked together by intermolecular C–H···O interactions.
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Kaynar, N.K., Ağar, E., Tanak, H. et al. Molecular and Crystal Structure of 2-{(E)-[(5-Chloro-2-methoxyphenyl)imino]methyl}-4-nitrophenol. Crystallogr. Rep. 63, 372–374 (2018). https://doi.org/10.1134/S1063774518030124
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DOI: https://doi.org/10.1134/S1063774518030124