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Synthesis and structure of heptaaqua{nitrilotris(methylenephosphonato)}(dibarium)sodium monohydrate [Na(H2O)3{μ6-NH(CH2PO3)3}(μ-H2O)3Ba2(H2O)] · H2O

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Abstract

Crystals of the monohydrate form of heptaaqua{nitrilotris(methylenephosphonato)}(dibarium) sodium [Na(H2O)3{µ6-NH(CH2PO3)3}(µ-H2O)3Ba2(H2O)] · H2O are obtained; space group P21/c, Z = 4; a = 13.9117(10) Å, b = 11.54030(10) Å, and c = 24.1784(17) Å, ß = 148.785(18)°. The Na atom is coordinated octahedrally by one oxygen atom of a phosphonate group and five water molecules, including two bridging molecules. Ba atoms occupy two inequivalent crystallographic positions with coordination number eight and nine. The coordination spheres of both Ba atoms include two water molecules. Each ligand is bound to one Na atom and five Ba atoms forming three Ba–O–P–O and five Ba–O–P–C–N–C–P–O chelate cycles. In addition to the coordination bonds, molecules, including the solvate water molecule, are involved in hydrogen bonds in the crystal packing.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603950, Russia

    N. V. Somov

  2. Physical–Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, 426000, Russia

    F. F. Chausov

  3. Udmurt State University, Izhevsk, 426034, Russia

    F. F. Chausov & R. M. Zakirova

Authors
  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, 2017, published in Kristallografiya, 2017, Vol. 62, No. 2, pp. 231–236.

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Somov, N.V., Chausov, F.F. & Zakirova, R.M. Synthesis and structure of heptaaqua{nitrilotris(methylenephosphonato)}(dibarium)sodium monohydrate [Na(H2O)3{μ6-NH(CH2PO3)3}(μ-H2O)3Ba2(H2O)] · H2O. Crystallogr. Rep. 62, 232–237 (2017). https://doi.org/10.1134/S1063774517020262

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  • DOI: https://doi.org/10.1134/S1063774517020262

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