Abstract
3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L 1, 1) and its Mn(II) complex, [Mn(L 1)2(SCN)2]∞ (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L 1 ligands, two SCN-ligands, and two oxygen atoms of other two L 1 ligands to form a distorted octahedral geometry. Therefore, each L 1 links Mn ions through the O and N atoms to generate 2D sheet structure.
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F. J. Smit, R. A. van Biljon, L.-M. Birkholtz, et al., Eur. J. Med. Chem, 90, 33 (2015).
L. Wang, G. Chen, X. Lu, et al., Eur. J. Med. Chem, 89, 88 (2015).
N. K. Konduru, S. Dey, M. Sajid, et al., Eur. J. Med. Chem, 59, 23 (2013).
S. K. Patle, N. Kawathekar, M. Zaveri, et al., Med. Chem. Res, 22, 1756 (2013).
Y. K. Yoon, M. A. Ali, A.C. Wei, et al., Bioor. Med. Chem, 22, 703 (2014).
W. Zhu, Y. Da, D. Wu, et al., Bioor. Med. Chem, 22, 2294 (2014).
G.-F. Wang, S.-W. Sun, Q.-P. Han, et al., Crystallogr. Rep. 59, 994 (2014).
G.-F. Wang, L. Chen, X.-J. Song, et al., Polyhedron 81, 550 (2014).
M.-D. Zhang, B.-H. Zheng, Y. Jiao, et al., Mendeleev Commun. 24, 180 (2014).
D. Maspoch, D. Ruiz-Molina, J. Veciana, Chem. Soc. Rev, 36, 770 (2007).
F. Jin, F.-X. Zhou, X.-F. Yang, et al., Polyhedron 43, 1 (2012).
W.-Q. Geng, H.-P. Zhou, L.-H. Cheng, et al., Polyhedron 31, 738 (2012).
G.-F. Wang, S.-W. Sun, Q.-J. Gong, et al., Crystallogr. Rep. 59, 988 (2014).
G.-F. Wang, Q.-J. Gong, H. Sun. et al., Crystallogr. Rep. 58, 1113 (2013).
T. Hussain, H. L. Siddiqui, M. Zia-ur-Rehman, et al., Eur. J. Med. Chem. 44, 4654 (2009).
G. M. Sheldrick, Program for Multi-Scan Absorption Correction (Univ. of Göttingen, Göttingen, Germany, 2000).
P. T. Beurskens, G. Admiraal. G. Beurskens, et al., The DIRDIF Program System, Technical Report of the Crystallography Laboratory (Univ. of Nijmegen, Nijmegen, The Netherlands, 1992), p. 92.
G. M. Sheldrick, Program for Crystal Structure Solution and Refinement (Univ. of Göttingen, Göttingen, Germany, 2000).
K. Iizuka, K. Akahane, D. I. Momose, et al., J. Med. Chem. 24, 1139 (1981).
Z.-Y. Zhang, S. Gao, L.-H. Huo, et al., Acta. Crystallogr. E 63, m1514 (2007).
M. D. L. Goodgame, S. Menzer, A. M. Smith, et al., Angew. Chem., Int. Ed. 34, 574 (1995).
S. Koda, S. Ooi, H. Kuroya, et al., J. Chem. Soc. D, 280 (1971).
B. Alvarez, C. Bois, Y. Jeannin, et al., Inog. Chem, 32, 3783 (1993).
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Wang, GF., Zhang, X., Sun, SW. et al. Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands. Crystallogr. Rep. 60, 1038–1043 (2015). https://doi.org/10.1134/S1063774515070305
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DOI: https://doi.org/10.1134/S1063774515070305