Abstract
The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k 3-N, N',N''-Tp t-Bu, MeNiI] (1) and [k 3-N,N',N''-Tp t-Bu, MeNiNO3] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II) ion of complex 1 is in a four-coordinate environment, in which the donor atoms are provided by three nitrogen atoms of a hydrotris(pyrazolyl) borate ligand and one iodide atom, while that of complex 2 is in a five-coordinate environment with three nitrogen atoms from a hydrotris(pyrazolyl)borate ligand and two oxygen atoms from a nitrate ion.
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References
S. Trofimenko, J. Amer. Chem. Soc. 88, 1842 (1966).
S. Trofimenko, Chem. Rev. 93, 943 (1966).
S. Trofimenko, Scorpionates, the Coordination Chemistry of Polypyrazolborate Ligands (Imperial College, London, 1999).
N. Kitajima and W. B. Tolman, Prog. Inorg. Chem. 43, 419 (1995).
A. P. Forshaw, J. M. Smith, A. Ozarowski, et al., Inorg. Chem. 52, 144 (2013).
W. Sattler and G. Parkin, Polyhedron 32, 41 (2012).
M. Galájov, C. M. Gómez, et al., Organometallics 33, 2277 (2014).
N. Chakrabarti, W. Sattler, and G. Parkin, Polyhedron 58, 235 (2013).
B. Quillian, E. E. Joslin, T. B. Gunnoe, et al., Inorg. Chem. 52, 1113 (2013).
E. E. Joslin, B. Quillian, T. B. Gunnoe, et al., Inorg. Chem. 53, 6270 (2014).
D. Naglav, D. Bläser, C. Wölper, and S. Schulz, Inorg. Chem. 53, 1241 (2014).
N. A. Foley, R. J. Abernethy, T. B. Gunnoe, et al., Organometallics 28, 374 (2009).
T. R. Cundari, T. V. Grimes, and T. B. Gunnoe, J. Amer. Chem. Soc. 129, 13172 (2007).
S. Trofimenko, J. C. Calabrese, J. K. Kocbi, et al., Inorg. Chem. 31, 3943 (1992).
R. Santi, A. M. Romano, A. Sommazzi, et al., J. Mol. Catal. A: Chem. 229, 191 (2005).
A. D. Beitelman and G. M. Ferrence, Acta Crystallogr. E 63, m2520 (2007).
P. J. Desrochers, J. Telser, S. A. Zvyagin, et al., Inorg. Chem. 45, 8930 (2006).
P. J. Desrochers, S. LeLievre, R. J. Johnson, et al., Inorg. Chem. 42, 7945 (2003).
S. Chattopadhyay, T. Deb, J. L. Petersen, et al., Inorg. Chem. 49, 457 (2010).
P. J. Desrochers, B. M. Besel, A. L. Corken, et al., Inorg. Chem. 50, 1931 (2011).
J. Krzystek, D. C. Swenson, S. A. Zvyagin, et al., J. Amer. Chem. Soc. 132, 5241 (2010).
Y.-J. Sun, W.-Z. Shen, P. Cheng, et al., Polyhedron 23, 211 (2004).
N. Kitajima, Bioinorganic Chemistry of Copper, Ed. by K. D. Karlin and Z. Tyeklar (Chapman & Hall, New York, 1993).
N. Kitajima and K. Fujisawa, J. Amer. Chem. Soc. 115, 4690 (1993).
N. Kitajima and Y. Moro-oka, Chem. Rev. 94, 737 (1994).
S. H. Cho, D. Whang, K. N. Han, and K. Kim, Inorg. Chem. 31, 519 (1992).
G. M. Sheldrick, Program for Multi-Scan Absorption Correction (Univ. of Göttingen, Göttingen, Germany, 2000).
G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).
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Wang, GF., Zhang, X., Sun, SW. et al. Synthesis and structural characterization of two half-sandwich nickel(II) complexes with the scorpionate ligands. Crystallogr. Rep. 60, 1032–1037 (2015). https://doi.org/10.1134/S1063774515070299
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DOI: https://doi.org/10.1134/S1063774515070299