Skip to main content
SpringerLink
Log in

Crystal structure of (Z)-3-methyl-4-((naphth-1-ylamino)methylidene)-1-phenyl-1H-pyrazol-5(4H)-one

  • Structure of Organic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The new pyrazolone derivative, (Z)-3-methyl-4-((naphthalen-1-ylamino)methylidene)-1-phenyl-1H-pyrazol-5(4H)-one, C21H17N3O, is synthesized, and its crystal structure is determined by X-ray structure analysis. The crystals are orthorhombic, sp. gr. P212121, a = 6.5683(7), b = 12.7384(15), c = 20.198(3) Å, Z = 4, R = 0.0564 for 983 observed reflections. In crystal, the molecule exists in amine-one tautomeric form. The crystal structure is stabilized by N–H···O and C–H···O hydrogen bonds. In addition, C–H···π and π-π-interactions are observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Xu and K. N. Raymond, Angew. Chem. Int. Ed. 39, 2745 (2000).

    Article  Google Scholar 

  2. F. Marchetti, C. Pettinari, and R. Pettinari, Coord. Chem. Rev. 249, 2909 (2005).

    Article  Google Scholar 

  3. J. S. Casas, M. S. García-Tasende, A. Sánchez, et al., Coord. Chem. Rev. 251, 1561 (2007).

    Article  Google Scholar 

  4. S. Gelin, B. Chantegrel, and A. I. Nadi, J. Org. Chem. 48, 4078 (1983).

    Article  Google Scholar 

  5. K. Hellmuth, S. Grosskopf, C. T. Lum, et al., Proc. Natl. Acad. Sci. USA 105, 7275 (2008).

    Article  ADS  Google Scholar 

  6. R. N. Jadeja and N. J. Parmar, Synth. React. Inorg. Met.-Org. Chem. 35, 111 (2005).

    Article  Google Scholar 

  7. B. T. Thakar, K. R. Surati, S. Oswal, et al., Struct. Chem. 18, 295 (2007).

    Article  Google Scholar 

  8. G. M. Sheldrick, Acta Crystallogr. A 64, 1/2 (2008).

    Article  Google Scholar 

  9. L. J. Farrugia, J. Appl. Crystallogr. 45, 849 (2012).

    Article  Google Scholar 

  10. M. Nardelli, Appl. Crystallogr. 28, 659 (1995).

    Article  Google Scholar 

  11. A. L. Spek, Acta Crystallogr. D 65, 148 (2009).

    Article  Google Scholar 

  12. L. J. Farrugia, J. Appl. Crystallogr. 30, 565 (2012).

    Article  Google Scholar 

  13. R. N. Jadeja, J. R. Shah, E. Suresh, and P. Paul, Polyhedron 23, 2465 (2004).

    Article  Google Scholar 

  14. P. J. Lapassent and J. Falgueirettes, Acta Crystallogr. B 28, 791 (1972).

    Article  Google Scholar 

  15. N. Sharma, S. Parihar, R. N. Jadeja, et al., Acta Crystallogr. E 70, o955 (2014).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi, 180 006, India

    N. Sharma, R. Kant & V. K. Gupta

  2. Department of Chemistry, Faculty of Science, The M.S. University of Baroda, Vadodara, 390002, India

    S. Parihar & R. N. Jadeja

Authors
  1. N. Sharma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Parihar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. N. Jadeja
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Kant
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. K. Gupta
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. K. Gupta.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharma, N., Parihar, S., Jadeja, R.N. et al. Crystal structure of (Z)-3-methyl-4-((naphth-1-ylamino)methylidene)-1-phenyl-1H-pyrazol-5(4H)-one. Crystallogr. Rep. 60, 1131–1135 (2015). https://doi.org/10.1134/S106377451507024X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106377451507024X

Keywords

Search

Navigation