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Synthesis and structure of a 2D → 3D framework with coexistence of hydrogen bonds and polythreading character

  • Structure of Organic Compounds
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Abstract

The title complex, {[Co(BPPA)(5-OH-bdc)] · (H2O)} n was prepared under hydrothermal conditions based on two ligands, namely, bis(4-(pyridin-4-yl)phenyl)amine (BPPA) and 5-hydroxyisophthalic acid (5-OH-H2 bdc). 5-OH-bdc 2– anions coordinated to Co atoms to give layers in crystal. BPPA ligands coordinate to Co atoms and thread into the adjacent layers. There are hydrogen bonds between adjacent layers, giving rise to a 2D → 3D framework.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment & Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, 210044, Jiangsu, P. R. China

    Ming-Dao Zhang, Qi-Fan Zhuang, Jing Xu & Hui Cao

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, 210093, Beijing, P. R. China

    Ming-Dao Zhang

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  1. Ming-Dao Zhang
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  2. Qi-Fan Zhuang
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  3. Jing Xu
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  4. Hui Cao
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Correspondence to Ming-Dao Zhang.

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Zhang, MD., Zhuang, QF., Xu, J. et al. Synthesis and structure of a 2D → 3D framework with coexistence of hydrogen bonds and polythreading character. Crystallogr. Rep. 60, 1106–1110 (2015). https://doi.org/10.1134/S1063774515070172

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  • DOI: https://doi.org/10.1134/S1063774515070172

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