Abstract
Reaction of 2-(1-methyl-1,2-dihydroimidazol-3-yl)acetonitrile tetrafluoroborate with silver oxide in dichloromethane readily yields [Ag(DIM)2]BF4, where DIM is 2-(1-methyl-1, 2-dihydroimidazol-3-yl)acetonitrile, representing a carbene organic ligand. The title compound was characterized by elemental analysis, IR, MS and single crystal X-ray diffraction. The crystal is of monoclinic system, space group C2/c with a = 14.010(18), b = 8.303(11), c = 14.936(20) Å, β = 93.910(4)°, V = 1639(4) Å3, Z = 4, D x = 1.771 g/cm3, F (000) = 864, µ(MoK α) = 1.278 mm–1. The final R 1 = 0.0711 and wR 2 = 0.1903 for reflections with I > 2σ(I). In addition, the preliminary biological test showed that the title compound had anti-fungus yeast activity.
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A. J. Arduengo III, R. L. Harlow, and M. Kline, J. Am. Chem. Soc. 113, 361 (1991).
A. Melaiye, Z. H. Sun, K. Hindi, et al., J. Am. Chem. Soc. 127, 2285 (2005).
H. J. Wang and J. B. Lin, Organometallics 17, 972 (1998).
A. Melaiye, R. S. Simons, A. Milsted, et al., J. Med. Chem. 47, 973 (2004).
A. Kascatan-Nebioglu, A. Melaiye, K. Hindi, et al., J. Med. Chem. 49, 6811 (2006).
K. M. Hindi, T. J. Siciliano, S. Durmus, et al., J. Med. Chem. 51, 1577 (2008).
K. M. Hindi, M. J. Panzner, C. A. Tessier, et al., Chem. Rev. 109, 3859 (2009).
M. L. Teyssot, A. S. Jarrousse, M. Manifestation, et al., Dalton Trans. 35, 6894 (2009).
B. Thati, A. Noble, B. S. Creaven, et al., Cancer Lett. 248, 321 (2007).
H. L. Zhu, X. M. Zhang, X. Y. Liu, et al., Inorg. Chem. Commun. 6, 1113 (2003).
J. J. Liu, P. Galettis, A. Farr, et al., J. Inorg, Biochem. 102, 303 (2008).
G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).
C. Sowjanya, V. RamaBharathi, G. Kalpana Devi, et al., J. Chem. Pharm. Res. 3, 212 (2011).
A. Elaiwi, P. B. Hitchcock, K. R. Seddon, et al., J. Chem. Soc, Dalton Trans. 3, 3467 (1995).
D. Zhao, Z. Fei, R. Scopelliti, et al., Inorg. Chem. 43, 2197 (2004).
V. J. Catalano, M. A Malwitz, A. O. Etogo, Inorg. Chem. 43, 5714 (2004).
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Jiu-Fu, L., Hong-Guang, G. & Juan, S. Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative. Crystallogr. Rep. 60, 1089–1092 (2015). https://doi.org/10.1134/S1063774515070159
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DOI: https://doi.org/10.1134/S1063774515070159