Abstract
A cadmium bipyridinium compound (CdCl4)(N,N'-dimethyl-2,2'-bipyridinium), in which the (N,N'-dimethyl-2,2'-bipyridinium)2+ moieties were generated in situ, has been prepared via solvothermal reactions and structurally characterized with single crystal X-ray diffraction method. Fluorescence measurement revealed a broad and strong emission band in the blue region.
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J. B. Waters, R. S. P. Turbervill, and J. M. Goicoechea, Organometallics. 32, 5190 (2013).
B. Mohapatra and S. Verma, Cryst. Growth Des. 13, 2716 (2013).
J. L. Chen, X. F. Cao, W. Gu, et al., Inorg. Chem. Commun. 15, 65 (2012).
M. Bardaji, A. B. Miguel-Coello, and P. Espinet, Inorg. Chim. Acta 386, 93 (2012).
F. L. Hu and X. H. Yin, Inorg. Chem. Commun. 15, 256 (2012).
M. Al-Noaimi and M. A. AlDamen, Inorg. Chim. Acta. 387, 45 (2012).
K. Amakawa, S. Wrabetz, J. Kröhnert, et al., J. Am. Chem. Soc. 134, 11462 (2012).
S. Cheong, J. Watt, B. Ingham, et al., J. Am. Chem. Soc. 131, 14590 (2009).
Rigaku (2002), CrystalClear Version 1.35 (Rigaku Corporation).
Siemens (1994). SHELXTLTM Version 5. Reference Manual (Siemens Energy & Automation Inc., Madison, Wisconsin, USA).
Q. G. Zhai, C. C. Zhang, S. N. Li, et al., Inorg. Chem. Commun. 14, 1982 (2011).
G. H. Eom, J. H. Kim, Y. D. Jo, et al., Inorg. Chim. Acta. 387, 106 (2012).
S. Satapathi, S. Choubey, K. Bhar, et al., Inorg. Chim. Acta. 384, 37 (2012).
Y. J. Chang, D. Liu, Z. G. Ren, et al., Inorg. Chem.Commun. 14, 403 (2011).
J. Wu, P. Wang, C. Huang, et al., Inorg. Chem. Commun. 15, 301 (2012).
I. D. Brown and D. Altermat, Acta Crystallogr. B 41, 244 (1985).
K. Yu., B. Zhou, Y. Yu, et al., Inorg. Chem. Commun. 14, 1846 (2011).
L. N. Xiao, Y. Wang, Y. Peng, et al., Inorg. Chim. Acta. 387, 204 (2012).
T. Mochida, Y. Funasako, T. Kishida, et al., Inorg. Chim. Acta 384, 111 (2012).
Y. Yang, S. Liu, C. Li, et al., Inorg. Chem. Commun. 17, 54 (2012).
C. C. Wang, Asian J. Chem. 21, 7211 (2009).
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Luo, H., Zhu, LC. & Wang, Q. Synthesis and characterization of a cadmium bipyridinium compound (CdCl4)(N,N'-dimethyl-2,2'-bipyridinium). Crystallogr. Rep. 60, 1080–1083 (2015). https://doi.org/10.1134/S106377451507010X
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DOI: https://doi.org/10.1134/S106377451507010X